化学计量比、雾化压力对电站锅炉SNCR脱硝的影响

引言 电厂锅炉作为化学能向蒸汽热能转换的一种设备,是火电生产过程中一个重要的环节.但是,锅炉燃烧化石燃料进行能量转化的同时也向环境排放了各种污染物质.

Impact of NSR and atomization pressure on SNCR used in power plant boiler

SNCR (selective non-catalytic reduction) using urea solution was used in a HG-410/9.8-YW15 boiler, whose combustion system included a pulverized-coal reburning system to control NO_x production.Tests were carried out at the load of 280 t•h^-1 ,345 t•h^-1 and 410 t•h^-1 .The experimental results showed that NO_x emission could be reduced under 200 mg•m^-3 (standard condition, 6%O₂, dry gas) with the SNCR system running.The increment of NSR (normalized stoichiometric ratio) resulted in an improvement of NO_x reduction efficiency, but the improvement was weak when NSR was greater than 2.5.A greater NSR also resulted in more ammonia slip, especially when NSR was greater than 1.25.N₂O emission reached the maximum as NSR was about 2.0.Ammonia slip increased and the existence time of the urea solution droplets decreased with increasing atomization steam pressure and the track distance of the droplets reached the maximum at an intermediate pressure.There was an optimal atomization steam pressure, which would result in the highest NO_x reduction efficiency of SNCR.And there was another optimal pressure of atomization steam, about 0.3 MPa, which would result in the least N₂O emission.