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臭氧高级氧化技术深度处理气田钻井废水应用研究
引用本文:张博廉,刘锐,顾寒松,操卫平,赵继伟.臭氧高级氧化技术深度处理气田钻井废水应用研究[J].广东化工,2013(20):50-51.
作者姓名:张博廉  刘锐  顾寒松  操卫平  赵继伟
作者单位:四川仁智石化科技有限责任公司,四川绵阳621000
摘    要:文章以气田钻井废水为研究对象,对经过混凝破胶处理后的废水进行臭氧氧化处理,探究了臭氧单独氧化、O3/H2O2氧化、O3/Fe2+氧化去除CODcr的最优处理条件.研究表明:在三种氧化方法中,O3/H2O2氧化具有最好的CODcr去除效果,其最优反应条件为在pH=10,臭氧投加量为0.5 g/h·L双氧水投加量为0.4%,氧化2h后废水的CODcr去除率可达69.1%.

关 键 词:钻井废水  奥氧氧化  深度处理

Study on Advanced Ozone Oxidation Processes in Gas Drilling Wastewater Disposal
Zhang Bolian,Liu Rui,Gu Hansong,Cao Weiping,Zhao Jiwei.Study on Advanced Ozone Oxidation Processes in Gas Drilling Wastewater Disposal[J].Guangdong Chemical Industry,2013(20):50-51.
Authors:Zhang Bolian  Liu Rui  Gu Hansong  Cao Weiping  Zhao Jiwei
Affiliation:(SiChuan Renzhi Petrochemical Technology Co., Ltd., Mianyang 621000, China)
Abstract:The paper takes gas drilling wastewater as the research object. The wastewater treatment by coagulation and gel breaking was oxidized by ozone. The optimum conditions of ozone oxidation, ozone/hydrogen peroxide oxidation and ozone/ferrous ion oxidation for CODCr removal were studied. The result shows ozone/hydrogen peroxide has the best CODCr removal efficiency, when the dosing quantity of ozone was 0.5 g/h·L and hydrogen peroxide was 0.4 %, the oxidation ptt was 10 and the oxidation time was 2 hours, the CODCr removal efficiency was the optimum, the CODCr removal rate reaches 69.1%.
Keywords:drillingwastewater  ozone oxidation  deep disposal
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