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T202型催化剂在焦炉气二级加氢脱硫工艺中的应用
引用本文:裴学国,亓栋,丁卉,王鲲,刘其智,刘金辉,郭玉峰.T202型催化剂在焦炉气二级加氢脱硫工艺中的应用[J].化肥设计,2011,49(5):48-51.
作者姓名:裴学国  亓栋  丁卉  王鲲  刘其智  刘金辉  郭玉峰
作者单位:1. 兖矿国际焦化有限公司,山东兖州,272100
2. 三聚环保新材料股份有限公司,北京,100080
摘    要:在以焦炉气为原料生产甲醇的二级加氢转化精脱硫工艺中使用了T202型铁钼加氢转化催化剂;介绍了该催化剂的反应机理、技术指标和铁钼催化剂二级加氢转化精脱硫的工艺流程;通过转化率、副反应、热点温度以及合成新鲜气的总硫分析数据对比,总结了技改效果。结果表明,组合预加氢、一级加氢及二级加氢工艺,可以满足不同有机硫化物含量的焦炉气...

关 键 词:T202型铁钼催化剂  焦炉气  加氢  脱硫工艺

Application for T202 Type Catalyst in Hydrogenation Desulphurization Process of Coking-Oven Gas in 2 Stages
PEI Xue-guo,QI Dong,DING Hui,WANG Kun,LIU Qi-zhi,LIU Jin-hui,GUO Yu-feng.Application for T202 Type Catalyst in Hydrogenation Desulphurization Process of Coking-Oven Gas in 2 Stages[J].Chemical Fertilizer Design,2011,49(5):48-51.
Authors:PEI Xue-guo  QI Dong  DING Hui  WANG Kun  LIU Qi-zhi  LIU Jin-hui  GUO Yu-feng
Affiliation:PEI Xue-guo,QI Dong,DING Hui,WANG Kun,LIU Qi-zhi,LIU Jin-hui,GUO Yu-feng (1.Yankuang International Coking Company Ltd.,Yanzhou Shandong 272100 China,2.Sanju Environment Protection New Material Stock Company Ltd.,Beijing 100080 China)
Abstract:T202 type Fe-Mo hydrogenation conversion catalyst has been used in second stage of hydrogenation conversion fine desulphurization process taking coking-oven gas as the raw material for producing methanol;author has introduced the reaction mechanism,technical index of this catalyst and the process flow for second stage of hydrogenation conversion fine desulphurization using Fe-Mo catalyst;through total sulfur analysis data comparison for conversion rate,by-reaction,hot point temperature and fresh synthetic gas,has summarized the technical reformation effect,result indicates that the first stage and second hydrogenation processes can satisfy the deep purification requirement for coking-oven gas containing various organic sulfide content.
Keywords:T202 type of Fe-Mo catalyst  coking——oven gas  hydrogenation  desulphurization process
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