| 过氧酸预处理时过氧酸与木素的反应机理 |
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| 引用本文： | 赵建,石淑兰.过氧酸预处理时过氧酸与木素的反应机理[J].纤维素科学与技术,1998,6(3):59-64. |
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| 作者姓名： | 赵建 石淑兰 |
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| 作者单位： | 天津轻工业学院造纸研究室!天津，300222，天津轻工业学院造纸研究室!天津，300222，天津轻工业学院造纸研究室!天津，300222 |
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| 摘 要： | 综述了过氧酸溶液（过氧乙酸、过氧一硫酸、混合过氧酸和二甲基二环氧乙烷）在预处理浆料时过氧酸与本素之间反应的有关机理，阐述了过氧酸预处理提高后续氧脱木凳的选择性，改善氧脱木素效果的原因。过氧酸作为一类具有很强氧化性的无氯漂剂，随着有关技术的日益发展和完善，完全可以代替有氯漂剂从而实现氯漂白。
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| 关 键 词： | 过氧酸 木素 机理 预处理 |
The reaction mechanism of peroxyacid and lignin during peroxyacid pretreatment |
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| Zhao Jian, Shi Shulan,Hu Huiren.The reaction mechanism of peroxyacid and lignin during peroxyacid pretreatment[J].Journal of Cellulose Science and Technology,1998,6(3):59-64. |
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| Authors: | Zhao Jian Shi Shulan Hu Huiren |
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| Abstract: | This paper summarizes the reaction mechanism of peroxyacid and lignin during pretreatment pulp with peroxyacid solutions, and explain the reason that pretreatment pulp with peroxyacid solutions can improve delignification selectivity and delignification degree in subsequent oxygn stage. These peroxyacids including peracehc acid (Pa), peroxymonosulfuric acid (Px),mixed peroxyocid(Pxa, a mixtur of peroxymonosulfuric acid and peracetic acid) and dimethyldioxiarane(DMD). Peroxyacids, as a strong oxidizing non - chlorine chemied agent, can be used in non - chlorine bleaching sequences instead of chlorine and chlorine - containing chemicals. |
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| Keywords: | peroxyacid lignin mechanism pretreatment |
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