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含硫酸盐还原菌土壤中阴极保护对Q235钢腐蚀的影响
引用本文:李国华,孙成,齐文元,刘霞,韩恩厚.含硫酸盐还原菌土壤中阴极保护对Q235钢腐蚀的影响[J].腐蚀科学与防护技术,2005,17(6):379-383.
作者姓名:李国华  孙成  齐文元  刘霞  韩恩厚
作者单位:1. 新疆油田分公司,油气储运公司,克拉玛依,834002
2. 中国科学院金属研究所,金属腐蚀与防护国家重点实验室,沈阳,110016
基金项目:中国科学院资助项目;教育部科学技术研究项目;科技部科技基础条件平台建设计划
摘    要:利用交流阻抗测试技术、扫描电镜及表面能谱、微生物分析等方法,研究了阴极保护对土壤中Q235钢硫酸盐还原菌腐蚀的影响.30天的实验结果表明,在相同的阴极极化电位下,有菌土壤中Q235钢所需要的阴极极化电流密度均大于灭菌土壤,有菌土壤中Q235钢的平均腐蚀速率均大于灭菌土壤.随着阴极极化电位负移的增大,有菌及灭菌土壤中Q235钢试件周围土壤逐渐呈碱性,有菌土壤中Q235钢试件周围土壤中硫酸盐还原菌数量逐渐减少,当阴极极化电位为-1050 mV时,Q235钢试件周围土壤中硫酸盐还原菌仍能够存活.

关 键 词:土壤  Q235钢  还原菌  阴极保护
文章编号:1002-6495(2005)06-0379-05
收稿时间:2004-04-14
修稿时间:2005-04-27

EFFECTS OF CATHODIC PROTECTION ON CORROSION OF Q235 STEEL IN SRB CONTAINING SOILS
LI Guo-hua,SUN Cheng,QI Wen-yuan,LIU Xia,HAN An-hou.EFFECTS OF CATHODIC PROTECTION ON CORROSION OF Q235 STEEL IN SRB CONTAINING SOILS[J].Corrosion Science and Protection Technology,2005,17(6):379-383.
Authors:LI Guo-hua  SUN Cheng  QI Wen-yuan  LIU Xia  HAN An-hou
Affiliation:1. Xingjiang Oil Field Branch, PLC, Kelamayi 834002; 2. State Key Lab. for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
Abstract:The effects of sulfate reducing bacterial(SRB) on cathodic protection of Q235 steel in soils have been studied,using bacterial analyses,electrochemical impedance spectroscopy(EIS),scanning electron microscopy (SEM) and EDS.The results showed that with increasing applied cathodic potential,pH value of soil gradually increased,the number of SRB and corrosion rate of Q235 steel decreased,and cathodic protection efficiency increased.At a cathodic potential of-1050 mV,SRB could still survive in soil around the sample of Q235 steel.At the same cathodic potential,the cathodic protection efficiency in soil without SRB was higher than that with SRB,and the corrosion rate of Q235 steel in soil with SRB was obviously larger than that without SRB.At the same cathodic potential,the cathodic current density needed for Q235 steel in soil with SRB was also larger than that without SRB.
Keywords:Q235 steel  soils  sulfate-reducing bacteria(SRB)  cathodic protection
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