| 顶空固相微萃取-气相色谱质谱联用分析汉麻叶挥发性成分 |
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| 引用本文： | 朱晨瑜,曹蕊,蒋勇,祝钧,何聪芬,何锦风.顶空固相微萃取-气相色谱质谱联用分析汉麻叶挥发性成分[J].北京轻工业学院学报,2012(4):44-49. |
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| 作者姓名： | 朱晨瑜 曹蕊 蒋勇 祝钧 何聪芬 何锦风 |
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| 作者单位： | [1]北京工商大学食品学院／植物资源研究开发北京市重点实验室,北京100048 [2]国家食品药品监督管理局保健食品审评中心,北京100070 [3]中国人民解放军总后勤部军需装备研究所军用汉麻材料研究中心,北京100082 |
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| 基金项目： | 汉麻植物中抗菌等成分提取及应用研究项目（19000551038） |
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| 摘 要： | 采用顶空固相微萃取法结合气相色谱-质谱联用对汉麻叶的挥发性成分进行分析,考察3种不同萃取纤维（DVB/CAR/PDMS,CAR/PDMS,PDMS/DVB）对分析结果的影响,结果表明较佳萃取纤维为CAR/PDMS.从汉麻叶中检出59种挥发性成分,占挥发油总组分的93.18%,其中醛类3种（0.71%）、醇类1种（0.06%）、烃类37种（57.23%）、杂环化合物类3种（0.19%）、萜烯类12种（34.49%）、其他3种（0.50%）.在鉴定出的成分中含量较多的是1R-（1R＊,4Z,9S＊）]-4,11,11-三甲基-8-亚甲基-二环7.2.0]4-十一烯（18.81%）、（1α,3α,5α）-1,5-二甲基-3-甲基-2-亚甲基环己烷（18.18%）、α-石竹烯（11.52%）、异柠檬烯（6.78%）等.
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| 关 键 词： | 汉麻 顶空固相微萃取 气相色谱-质谱 挥发性成分 |
Headspace Solid-phase Microextraction and GC-MS Analysis of Volatile Components of China-Hemp Leaves |
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| ZHU Chen-yu,CAO Rui,JIANG Yong,ZHU Jun,HE Cong-fen,HE Jin-feng.Headspace Solid-phase Microextraction and GC-MS Analysis of Volatile Components of China-Hemp Leaves[J].Journal of Beijing Institute of Light Industry,2012(4):44-49. |
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| Authors: | ZHU Chen-yu CAO Rui JIANG Yong ZHU Jun HE Cong-fen HE Jin-feng |
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| Affiliation: | 1. School of Food and Chemical Engineering/Beijing Key Laboratory of Plant Resources and Development, Beijing Technology and Business University, Belting 100048, China ; 2. The State Food and Drug Administration Center for Health Food Evaluation,Beijing 100070, China; 3. Research Center of China-Hemp Materials, Quartermaster Research Institute, General Logistic Department of Chinese People＇s Liberation Army, Beijing 100082, China) |
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| Abstract: | The volatile components of China-Hemp leaves were extracted by headspace solid-phase micro- extraction （HS-SPME） apparatus with three different fibers （divinylbenzene/earboxen/polydimethylsilox- ane DVB/CAR/PDMS, carboxen/polydimetylsiloxane CAR/PDMS, polydimetylsiloxane/divinylbenzene PDMS/DVB）. The results showed that the fiber of CAR/PDMS had the best extraction efficiency. A total of 59 compounds were analyzed and identified by gas chromatography-mass spectrometry（GC-MS）. The volatile components were accounted for 93. 18% in total, including 3 aldehydes（0. 71% ）, 1 alcohol （0.06%）, 37 hydrocarbons（57.23% ） 3 heterocyclie compounds（0. 19% ）, 12 terpenoids（34.49% ） and 8 other compounds （25.64%）. The prominent compounds were 1 R-（ 1R ＊ ,4Z ,9S ＊ ）] 4,11,11- Trimethyl-8-methylene-bieyclo 7.2.0 ] undee-4-ene （ 18.81% ）, （ 1 a, 3 a, 5 a ） -1,5 -Diethenyl-3 -methyl- 2-methylene-cyclohexane （ 18. 18 % ）, a-Caryophyllene （ 11.52 % ）, （ 3 R-trans ） -3-Methyl-6- （ 1 -methyle- thenyl） -cyclohexene （ 6.78 % ） etc. |
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| Keywords: | China-Hemp headspace solid-phase microextraction gas chromatography-mass spectrometry volatile components |
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