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废轮胎热解炭黑的表面修饰及其在平版印刷油墨中的应用
引用本文:周洁,王靖岱,任晓红,阳永荣,蒋斌波.废轮胎热解炭黑的表面修饰及其在平版印刷油墨中的应用[J].中国化学工程学报,2006,14(5):654-659.
作者姓名:周洁  王靖岱  任晓红  阳永荣  蒋斌波
作者单位:浙江大学;浙江大学;浙江大学;浙江大学;浙江大学
基金项目:国家自然科学基金,国家自然科学基金
摘    要:Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) is one of the most important products resulting from the pyrolysis of used tires. One of the most significant applications of modified pyrolytic carbon black is its use as pigment for offset printing ink to obtain high added values. Inverse gas chromatography (IGC) results show that a large quantity of inorganic matters and carbonaceous deposit are removed by treating the pyrolytic carbon black with nitric acid solution. Plenty of active sites originally occupied by inorganic ash and coke are recovered. The surface energy of pyrolytic carbon black (TWPC) modified by titanate-coupling agent-especially the specific interaction γs^SP determined by the specific probe molecule, toluene-shows the strong interaction between the TWPC and the synthetic resins. The offset printing ink performance confirms the IGC prediction. And TWPC has the great potential of applications in printing ink industry as pigment.

关 键 词:废轮胎  热解  炭黑  表面修饰  平版印刷油墨
收稿时间:2005-07-22
修稿时间:2005-07-222006-03-02

Surface Modification of Pyrolytic Carbon Black from Waste Tires and Its Use as Pigment for Offset Printing Ink
ZHOUJie,WANGJingdai,RENXiaohong,YANGYongrong,JIANGBinbo.Surface Modification of Pyrolytic Carbon Black from Waste Tires and Its Use as Pigment for Offset Printing Ink[J].Chinese Journal of Chemical Engineering,2006,14(5):654-659.
Authors:ZHOUJie  WANGJingdai  RENXiaohong  YANGYongrong  JIANGBinbo
Affiliation:a. UNILAB Research Center for Chemical Reaction Engineering, Department of Chemical Engineering, Zhejiang University, Hangzhou 310027, China; b. Department of Environmental Science and Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
Abstract:Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) is one of the most important products resulting from the pyrolysis of used tires. One of the most significant applications of modified pyrolytic carbon black is its use as pigment for offset printing ink to obtain high added values.Inverse gas chromatography (IGC) results show that a large quantity of inorganic matters and carbonaceous deposit are removed by treating the pyrolytic carbon black with nitric acid solution. Plenty of active sites originally occupied by inorganic ash and coke are recovered. The surface energy of pyrolytic carbon black (TWPC) modified by titanate-coupling agent-especially the specific interaction γsPs determined by the specific probe molecule, toluene-shows the strong interaction between the TWPC and the synthetic resins. The offset printing ink performance confirms the IGC prediction. And TWPC has the great potential of applications in printing ink industry as pigment.
Keywords:environmental engineering  waste tires  ink
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