| 酰胺基卟啉化合物的制备、表征及热分析 |
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| 引用本文： | 王瑛,庄长福,张加研,吴春华,秦永剑,师同顺. 酰胺基卟啉化合物的制备、表征及热分析[J]. 应用化工, 2012, 41(2): 198-201 |
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| 作者姓名： | 王瑛 庄长福 张加研 吴春华 秦永剑 师同顺 |
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| 作者单位： | 1. 西南林业大学材料工程学院,云南昆明,650224
2. 吉林大学化学学院,吉林长春,130023 |
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| 基金项目： | 国家自然科学基金(31060099);云南省教育厅科学研究基金重点项目(2010Z040);西南林业大学重点学科建设项目资助(XKX200907) |
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| 摘 要： | 5-(4-氨基)苯基-10,15,20-三苯基卟啉(MATPP)与棕榈酸在CH2Cl2中直接反应,得到一种新型不对称酰胺基卟啉5-(4-棕榈酸酰亚胺基)苯基-10,15,20-三苯基卟啉(PITPPH2),利用紫外-可见光谱、红外光谱、核磁共振氢谱、元素分析等测试方法对化合物的结构加以确认。热分析表明,卟啉PITPPH2从200℃开始分解,具有较高的热稳定性。
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| 关 键 词： | 卟啉 合成 表征 热稳定性 |
Preparation, characterization and thermal stability of an imide porphyrin |
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| WANG Ying , ZHUANG Chang-fu , ZHANG Jia-yan , WU Chun-hua , QIN Yong-jian , SHI Tong-shun. Preparation, characterization and thermal stability of an imide porphyrin[J]. Applied chemical industry, 2012, 41(2): 198-201 |
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| Authors: | WANG Ying ZHUANG Chang-fu ZHANG Jia-yan WU Chun-hua QIN Yong-jian SHI Tong-shun |
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| Affiliation: | 1.Institute of Material Engineering,Southwest Forestry University,Kunming 650224,China;2.College of Chemistry,Jilin University,Changchun 130023,China) |
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| Abstract: | An unsymmetrical imide porphyrin ligand,5-(4-palmiticimidephenyl) phenyl-10,15,20-triphenyl porphyrin(PITPPH2) have been synthesized by the reaction of the palmitic acid and 5-(4-aminophenyl)-10,15,20-triphenylporphyrin(MATPP) in CH2Cl2.The PITPPH2 was characterized by UV-Vis spectra,mass spectra,elemental analysis,IR spectra and 1H NMR spectra.The thermal studies showed that the porphyrin PITPPH2 could be dried under 200 ℃ and had higher thermal stability. |
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| Keywords: | porphyrin synthesis characterization thermal stability |
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