Key Aspects of Catalyst Design for the Selective Oxidation of Paraffins

This review examines some aspects in the development of heterogenous catalysts for the oxyfunctionalization of light paraffins. Particular attention is devoted to the raction of paraffin oxydehydrogenation to olefins and of n-butane oxidation to maleic anhydride. Most catalyst compositions are based on vanadium oxide as the main component, and the peculiar properties of this element with respect to the catalytic performance are discussed. These properties are also examined in ligh of the stability of the product of partial oxidation towards consecutive unselective oxidation reactions, and with respect to the mechanism of paraffin activation.