Metal organic frameworks as electrocatalysts: Hydrogen evolution reactions and overall water splitting |
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Authors: | Meena Nemiwal Vijayalakshmi Gosu Tian C Zhang Dinesh Kumar |
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Affiliation: | 1. Department of Chemistry, Malaviya National Institute of Technology, Jaipur, 302017, India;2. Department of Chemical Engineering, Malaviya National Institute of Technology, Jaipur, 302017, India;3. Department of Civil & Environmental Engineering, University of Nebraska-Lincoln, Peter Kiewit Institute, Omaha, NE, 68182-0178, United States, USA;4. School of Chemical Sciences, Central University of Gujarat, Gandhinagar, 382030, India |
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Abstract: | The development of clean energy technologies to protect the environment is an important demand of the times. Electrocatalysis is emerging as a promising method for evolution of hydrogen and overall water splitting. Nowadays, metal organic frameworks (MOFs) have emerged as electrocatalysts having uniformly distributed active sites and high electrical conductivity. This review summarizes the latest advances in heterogeneous catalysis by MOFs and their composite/derivatives for efficient hydrogen evolution reaction (HER) and water splitting. Pristine MOFs with their recent development are summarized first followed by composites of MOFs with their enhanced electrocatalytic performances. Overall water splitting by using bifunctional electrocatalysts derived from MOFs with different synthetic approaches is provided and this review gives the metal-based categorisation of precursor MOFs. Different strategies to improve chemical stability, conductivity, and overall electrocatalytic properties have been discussed. In the last, perspectives on the synthesis of efficient MOF-based electrocatalyst materials are provided. |
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Keywords: | Metal organic frameworks Electrocatalysis Hydrogen evolution Overall water splitting |
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