|
|||||
|
|
| 水杨醛一步法合成邻羟基苯甲腈 | |
| 引用本文： | 陈强,廖文文,刘智凌.水杨醛一步法合成邻羟基苯甲腈[J].现代农药,2007,6(3):21-22,24. |
| 作者姓名： | 陈强 廖文文 刘智凌 |
| 作者单位： | 1. 江苏宝灵化工股份有限公司,江苏南通,226006 2. 湖南师范大学化学化工学院,长沙410082 3. 湖南化工研究院国家农药创制工程技术研究中心,长沙,410007 |
| 摘 要： | 以水杨醛为原料一步法生产邻羟基苯甲腈。61.5g(0.5mol)水杨醛、42g(0.6mol)盐酸羟胺和500mLN-甲基吡咯烷酮,110～115℃下反应5h,得产品邻羟基苯甲腈,摩尔收率91.2%,产品含量99%。 |
| 关 键 词： | 邻羟基苯甲腈 水杨醛 一步法合成 |
| 文章编号： | 1671-5284（2007）03-0021-02 |
| 收稿时间： | 2007-03-02 |
| 修稿时间： | 2007-03-02 |
One-pot Synthesis of 2-Hydroxybenzonitrile from Salicylaldehyde |
|
| CHEN Qiang,LIAO Wen-wen,LIU Zhi-ling.One-pot Synthesis of 2-Hydroxybenzonitrile from Salicylaldehyde[J].Modern Agrochemicals,2007,6(3):21-22,24. | |
| Authors: | CHEN Qiang LIAO Wen-wen LIU Zhi-ling |
| Affiliation: | 1. Jiangsu Baoling Chemical Co., Ltd., Jiangsu Nantong 226006, China; 2. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410082, China; 3. National Engineering Research Center for Agrochemicals, Hunan Reseach Institute of Chemical Industry, Changsha 410007, China |
| Abstract: | 2-Hydroxybenzonitrile was preprared in high yield in a one-pot process by reacting salicyladehyde with hydroxylamine hydrochloride in N-methylpyrrolidone at 110 to 115℃ for 5 h. After purification ,the yield of the product is 91.2% and content 99%. |
| Keywords: | 2-hydroxybenzonitrile salicylaldehyde one-pot synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |
