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Characteristics of dual‐type electrochromic devices based on poly(ethylene oxide) copolymers
Authors:Huseyin Bekir Yildiz  Elif Sahin  Ali Cirpan  Levent Toppare  Yusuf Yagci
Affiliation:1. Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey;2. Department of Chemistry, Dicle University, 21280 Diyarbakir, Turkey;3. Department of Polymer Science and Engineering, University of Massachusetts, 120 Governors Drive, Amherst, MA 01003, USA;4. Department of Chemistry, Middle East Technical University, 06531 Ankara, TurkeyDepartment of Chemistry, Middle East Technical University, 06531 Ankara, Turkey;5. Department of Chemistry, Istanbul Technical University, 80626 Istanbul, Turkey
Abstract:Dual‐type polymer electrochromic devices based on (3‐thienyl)methylmethacrylate]‐cop‐vinyl benzyloxy poly(ethylene oxide)]/polythiophene and thiophene‐capped poly(ethylene oxide)/polythiophene and ethylene dioxythiophene were constructed via electropolymerization. Spectroelectrochemistry, switching ability and stability of the devices were investigated using UV‐visible spectrophotometry and cyclic voltammetry. These devices exhibit low switching voltages and short switching times with reasonable switching stability under atmospheric conditions. Copyright © 2006 Society of Chemical Industry
Keywords:electrochromic polymer  electrochromic device  conducting polymer  poly(ethylene oxide)
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