| 锌锰异常共沉积的理论分析 |
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| 引用本文： | 缪娟,符德学,王拥军,舒余德.锌锰异常共沉积的理论分析[J].焦作工学院学报,2003,22(4):316-319. |
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| 作者姓名： | 缪娟 符德学 王拥军 舒余德 |
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| 作者单位： | [1]焦作工学院。河南焦作454000 [2]焦作大学化学工程系，河南焦作454100 [3]中南大学冶金科学与工程系，湖南长沙410083 |
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| 基金项目： | 河南省自然科学基金资助项目(0211062700) |
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| 摘 要： | 从合金电沉积电极和溶液界面各因素的变化对合金电沉积的影响出发,在考虑一般电极过程动力学的基础上,进一步考虑到电极表面、溶液双电层OHP面上状态的变化及放电离子和非放电离子在OHP面上的相互影响,提出了电极溶液界面层作用模型,以期揭示锌锰异常共沉积发生的原因。
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| 关 键 词： | 锌锰异常共沉积 电极溶液界面层作用模型 分析 |
A model of interfacial state between electrode and solution to explain the anomalous co-deposition of Zn and Mn |
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| MIAO Juan,FU DE-xue,WANG Yong-jun,SHU Yu-de.A model of interfacial state between electrode and solution to explain the anomalous co-deposition of Zn and Mn[J].Journal of Jiaozuo Institute of Technology(Natural Science),2003,22(4):316-319. |
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| Authors: | MIAO Juan FU DE-xue WANG Yong-jun SHU Yu-de |
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| Abstract: | The anomalous co-deposition of Zn and Mn is discussed in this paper. The main viewpoints are as follow: the consistence of different metal complex in OHP (Out Helmholtz Plate) affects the deposition of metal in cathode, other metal ions which do not reduce in cathode in the way of deposition of metal. The change of consistence in OHP is the main reason of anomalous co-depositionl. In the opinion of model of interfacial interaction, the kinetic of metal electro - deposition is obtained. The kinetic equation is corresponding to the fact of experiment. The difference change between izn and iMn with potential is the main cause of the anomalous co-deposition of Zn and Mn. |
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| Keywords: | the anomalous co-deposition of Zn and Mn Interfacial action model of alloy deposition analysis |
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