| 共混法制备酸性可染聚丙烯腈纤维 |
| |
| 引用本文： | 王雅珍,杜淑平,祖立武,宋武.共混法制备酸性可染聚丙烯腈纤维[J].合成纤维工业,2007,30(3):42-44. |
| |
| 作者姓名： | 王雅珍 杜淑平 祖立武 宋武 |
| |
| 作者单位： | 齐齐哈尔大学化学与化工学院,黑龙江,齐齐哈尔,161006 |
| |
| 摘 要： | 用含有碱性基团的丙烯酸氨基酯(TAM)与丙烯腈(AN)单体共聚,其共聚物与聚丙烯腈(PAN)共混,经湿法纺丝制备酸性染料可染PAN共混纤维。结果表明,AN／TAM共聚物与PAN有良好的相容性。随着TAM含量的增加,PAN共混纤维结晶度下降,力学性能下降。纤维中TAM质量分数5％较好,PAN共混纤维酸性染料上染率大于80％。
|
| 关 键 词： | 聚丙烯腈纤维 共混改性 湿法纺丝 共聚 酸性染料 |
| 文章编号： | 1001-0041（2007）03-0042-03 |
| 修稿时间： | 2006-09-212007-03-12 |
Preparation of acid dyeable polyacrylonitrile fiber via blending process |
| |
| Wang Yazhen,Du Shuping,Zu Liwu,Song Wu.Preparation of acid dyeable polyacrylonitrile fiber via blending process[J].China Synthetic Fiber Industry,2007,30(3):42-44. |
| |
| Authors: | Wang Yazhen Du Shuping Zu Liwu Song Wu |
| |
| Affiliation: | College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006 |
| |
| Abstract: | An acid dyeable polyacrylonitrile (PAN) blend fiber was prepared by blending polyacrylontrile and a copolymer syn-thesized from trihydroxy methyl-aminomethane (TAM) containing basic groups and acrylonitrile (AN) raonomr via wet spinning process. The results showed that AN/TAM copolymer showed a good compatibility with PAN. The mechanical properties and crystallinity of PAN blend fiber were decreased with the increase of TAM content. The acid dye up-take of the PAN blend fiber was over 80% when the mass fraction of TAM was 5%. |
| |
| Keywords: | polyacrylonitrile fiber blend modification wet spinning polymerization acid dyes |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
