Investigation on the miscibility of the blends of poly(methyl methacrylate) and poly(styrene‐co‐acrylonitrile) |
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Authors: | L Ren M Y Zhang YR Wang H Na H X Zhang |
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Affiliation: | 1. Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun, 130012, China;2. School of Chemical Engineering, Changchun University of Technology, Changchun, 130012, China;3. College of Chemistry, Jilin University, Changchun, 130012, China;4. Changchun Institute of Applied Chemistry, Graduate School, Chinese Academy of Sciences, Changchun, 130022, China |
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Abstract: | The miscibility was investigated in blends of poly(methyl methacrylate) (PMMA) and styrene‐acrylonitrile (SAN) copolymers with different acrylonitrile (AN) contents. The 50/50 wt % blends of PMMA with the SAN copolymers containing 5, 35, and 50 wt % of AN were immiscible, while the blend with copolymer containing 25 wt % of AN was miscible. The morphologies of PMMA/SAN blends were characterized by virtue of scanning electron microscopy and transmission electron microscopy. It was found that the miscibility of PMMA/SAN blends were in consistence with the morphologies observed. Moreover, the different morphologies in blends of PMMA and SAN were also observed. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 |
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Keywords: | miscibility PMMA/SAN blends morphologies SEM TEM |
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