| 含酚废水处理的吸附和臭氧氧化动力学模型 |
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| 作者姓名： | Wongsarivej Pratarn Tongprem Pornsiri Swasdisevi Thanit Charinpanitkul Tawatchai Tanthapanichakoon Wiwut |
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| 作者单位： | 1. National Nanotechnology Center, Thailand Science Park, Klong Luang, Pathumthani 12120, Thailand;2. School of Energy, Environment and Materials, King Mongkut’s University of Technology Thonburi, 126 Pracha u-tid Rd., Bangkok 10140, Thailand;3. Center of Excellence in Particle Technology, Faculty of Engineering, Chulalongkorn University, Payathai Rd., Wangmai, Pathumwan, Bangkok 10330, Thailand |
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| 基金项目： | Supported by the National Nanotechnology Center(NANOTEC)(601003); the National Science and Technology Development Agency(NSTDA) |
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| 摘 要： | A three phase fluidized bed reactor was used to investigate the combined effect of adsorption and oxidation for phenolic wastewater treatment.Aqueous solutions containing 10 mg·L 1of phenol and ozone were continuously fed co-currently as upward flow into the reactor at constant flow rate of 2 and 1 L·min1,respectively.The phenolic treatment results in seven cases were compared:(a)O3 only,(b)fresh granular activated carbon(GAC),(c) 1st reused GAC,(d)2nd reused GAC,(e)fresh GAC enhanced with O3,(f)1st reused GAC enhanced with O3,and (g)2nd reused GAC enhanced with O3.The phenolic wastewater was re-circulated through the reactor and its concentration was measured with respect to time.The experimental results revealed that the phenolic degradation using GAC enhanced with O3 provided the best result.The effect of adsorption by activated carbon was stronger than the effect of oxidation by ozone.Fresh GAC could adsorb phenol better than reused GAC.All cases of adsorption on GAC followed the Langmuir isotherm and displayed pseudo second order adsorption kinetics.Finally,a differential equation for the fluidized bed reactor model was used to describe the phenol concentration with respect to time for GAC enhanced with O3.The calculated results agree reasonably well with the experimental results.
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| 关 键 词： | adsorption ozonation kinetic model phenol wastewater |
| 收稿时间： | 2010-6-2 |
| 修稿时间： | 2010-12-27
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Adsorption and ozonation kinetic model for phenolic wastewater treatment |
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| Wongsarivej Pratarn,Tongprem Pornsiri,Swasdisevi Thanit,Charinpanitkul Tawatchai,Tanthapanichakoon Wiwut.Adsorption and ozonation kinetic model for phenolic wastewater treatment[J].Chinese Journal of Chemical Engineering,2011,19(1):76-82. |
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| Authors: | Wongsarivej Pratarn Tongprem Pornsiri Swasdisevi Thanit Charinpanitkul Tawatchai Tanthapanichakoon Wiwut |
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| Affiliation: | 1. National Nanotechnology Center, Thailand Science Park, Klong Luang, Pathumthani 12120, Thailand;2. School of Energy, Environment and Materials, King Mongkut’s University of Technology Thonburi, 126 Pracha u-tid Rd., Bangkok 10140, Thailand;3. Center of Excellence in Particle Technology, Faculty of Engineering, Chulalongkorn University, Payathai Rd., Wangmai, Pathumwan, Bangkok 10330, Thailand |
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| Abstract: | A three phase fluidized bed reactor was used to investigate the combined effect of adsorption and oxidation for phenolic wastewater treatment. Aqueous solutions containing 10 mg•L1 of phenol and ozone were continuously fed co-currently as upward flow into the reactor at constant flow rate of 2 and 1 L•min1, respectively. The phenolic treatment results in seven cases were compared: (a) O3 only, (b) fresh granular activated carbon (GAC), (c) 1st reused GAC, (d) 2nd reused GAC, (e) fresh GAC enhanced with O3, (f) 1st reused GAC enhanced with O3, and (g) 2nd reused GAC enhanced with O3. The phenolic wastewater was re-circulated through the reactor and its con-centration was measured with respect to time. The experimental results revealed that the phenolic degradation using GAC enhanced with O3 provided the best result. The effect of adsorption by activated carbon was stronger than the effect of oxidation by ozone. Fresh GAC could adsorb phenol better than reused GAC. All cases of adsorption on GAC followed the Langmuir isotherm and displayed pseudo second order adsorption kinetics. Finally, a differential equation for the fluidized bed reactor model was used to describe the phenol concentration with respect to time for GAC enhanced with O3. The calculated results agree reasonably well with the experimental results. |
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| Keywords: | adsorption ozonation kinetic model phenol wastewater |
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