The chemical anchoring of noble metal amine precursors to silica |
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| Authors: | W Zou RD Gonzalez |
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| Affiliation: | Department of Chemical Engineering, Tulane University, New Orleans, LA 70118, USA |
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| Abstract: | The effect of pretreatment on the dispersion of supported noble metal Catalyst prepared from amine precursors in basic solution have been studied. The following metal precursors were used: Pt(NH3)4(NO3)2, Pd(NH3)4(NO3)2, Ru(NH3)6Cl3 and Rh(NH3)5Cl]Cl2 Pretreatment in oxygen, prior to reduction in H2 at 400C, resulted in poor dispersions for Ru and Rh, moderate dispersions for Pd and high dispersions for Pt. Pretreatment in H2 resulted in poor dispersions for Pd and Pt and high dispersions for Ru and Rh. Decomposition of the adsorbed Pt and Pd precursors in argon resulted in very high dispersions. |
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