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磁性纳米材料Fe3O4-RGO-NH2对Ag+的吸附性能研究
引用本文:吴娟,贺沁婷,程庆霖,任芳,陈卓涵,赵雨,曾诗豪,张莹.磁性纳米材料Fe3O4-RGO-NH2对Ag+的吸附性能研究[J].贵金属,2021,42(3):15-20.
作者姓名:吴娟  贺沁婷  程庆霖  任芳  陈卓涵  赵雨  曾诗豪  张莹
作者单位:江苏理工学院 化学与环境工程学院,江苏 常州 213001
基金项目:国家自然科学基金青年项目(51902141);江苏省自然科学青年基金(BK20191038);常州市科技计划项目(CJ20210072);江苏理工学院人才引进项目(KYY17021);2021年大学生创新创业训练计划江苏省重点项目(202111463009Z)
摘    要:采用一步溶剂热法成功制备了新型磁性纳米吸附剂Fe3O4-RGO-NH2,用透射电子显微镜(TEM)、X射线衍射(XRD)、振动样品磁力计(VSM)及Zeta电势对其形貌及晶型结构进行了表征,研究了Fe3O4-RGO-NH2纳米吸附剂对水溶液中Ag+的吸附性能。结果表明,水溶液pH值对Ag+吸附具有很大影响,pH=4.0时吸附效果最佳。Ag+最大吸附量随着初始浓度及吸附时间的增加而增加,Ag+的吸附符合准二级动力学模型。

关 键 词:磁性  纳米吸附剂  制备  银离子(Ag+)  捕获性能
收稿时间:2020/12/17 0:00:00

Study on adsorption performance of magnetic nano material Fe3O4-RGO-NH2 for Ag+
WU Juan,HE Qin-ting,CHENG Qing-lin,REN Fang,CHEN Zhuo-han,ZHAO Yu,ZENG Shi-hao,ZHANG Ying.Study on adsorption performance of magnetic nano material Fe3O4-RGO-NH2 for Ag+[J].Precious Metals,2021,42(3):15-20.
Authors:WU Juan  HE Qin-ting  CHENG Qing-lin  REN Fang  CHEN Zhuo-han  ZHAO Yu  ZENG Shi-hao  ZHANG Ying
Affiliation:School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, Jiangsu, China
Abstract:A new type of magnetic nano-adsorbent Fe3O4-RGO-NH2 was successfully prepared by one-step solvothermal method. The morphology and crystal structure of the prepared Fe3O4-RGO-NH2 nano-adsorbent were characterized by transmission electron microscopy(TEM), X-ray diffraction(XRD), vibrating sample magnetometer(VSM) and Zeta potential. The adsorption performance of Fe3O4-RGO- NH2 nano-adsorbent for Ag+ in aqueous solution was studied. The results showed that the pH value of the aqueous solution had a major impact on Ag+ adsorption, and that the adsorption effect was the best when pH=4.0. The maximum adsorption capacity of Ag+ increases with initial concentration and adsorption time, and the adsorption process of Ag+ is the pseudo-second-order kinetics model.
Keywords:magnetism  nano-adsorbent  preparation  silver ions (Ag+)  capture performance
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