Synthesis and properties of poly(amide-imide)s based on 1,5-bis(4-trimellitimido)naphthalene |
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Authors: | Chin-Ping Yang Sheng-Huei Hsiao Ming-Ru Tsai |
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Affiliation: | (1) Department of Chemical Engineering, Tatung Institute of Technology, 40 Chungshan North Rd. Sec. 3, Taipei, 10451, Taiwan, ROC |
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Abstract: | 1,5-Bis(4-trimellitimido)naphthalene (II) was prepared by the condensation reaction of 1,5-naphthalenediamine and trimellitic anhydride. A series of aromatic poly(amide-imide)s
(IV
a–o) was synthesized by the direct polycondensation of the diimide-diacid (II) and various aromatic diamines (III
a–o). The reaction utilized triphenyl phosphite and pyridine as condensing agents in the presence of calcium chloride in N-methyl-2-pyrrolidone (NMP). The inherent viscosities of the resulting poly(amide-imide)s were in the range of 0.55∼1.39 dL/g.
These polymers were generally soluble in polar solvents, such as N,N-dimethylacetamide (DMAc), NMP, N,N-dimethylformamide (DMF). Flexible and tough poly(amide-imide) films were obtained by casting from a DMAc solution and had
tensile strengths of 90∼145 MPa, elongations to break of 5∼13 %, and initial moduli of 2.29∼3.73 GPa. The glass transition
temperatures of some poly(amide-imide)s were recorded in the range of 206∼218 °C, and most of the polymers did not show discernible
glass transition on their DSC traces. The 10% weight loss temperatures were above 522 °C in nitrogen and above 474 °C in air
atmosphere. |
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Keywords: | Poly(amide-imide)s 1 5-Naphthalenediamine Trimellitic anhydride |
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