| 聚羧酸硅基酯的合成及其可降解性质的研究进展 |
| |
| 引用本文： | 韩念凤,刘宗林,王勤,夏毅然.聚羧酸硅基酯的合成及其可降解性质的研究进展[J].中国塑料,2005(8). |
| |
| 作者姓名： | 韩念凤 刘宗林 王勤 夏毅然 |
| |
| 作者单位： | 山东大学化学与化工学院，山东大学化学与化工学院，山东医疗器械研究所，山东医疗器械研究所 山东 济南 250100，山东 济南 250100，山东 济南 250100，山东 济南 250100 |
| |
| 基金项目： | 国家自然科学基金资助项目(20274022) |
| |
| 摘 要： | 综述了聚羧酸硅基酯的合成方法和降解性质。用于合成聚羧酸硅基酯的方法主要有AA/BB型硅基转移酯基交换法、AB型硅基转移酯基交换法、AB型硅氢化反应以及交叉去氢偶联反应。对上述方法的特点进行了总结和比较。详细介绍了该类聚合物的降解机理以及影响降解速率的因素,并对其在生物医学以及环境科学领域的应用进行了展望。
|
| 关 键 词： | 聚羧酸硅基酯 合成方法 可降解性 |
Research Progress in Preparation and Degradation Behavior of Poly(carboxylic acid silyl ester)s |
| |
| HAN Nian-feng , LIU Zong-lin , WANG Qin , XIA Yi-ran .School of Chemistry and Chemical Engineering,Shandong University,Jinan ,China, .Shandong Medical Instrument Institute,Jinan ,China.Research Progress in Preparation and Degradation Behavior of Poly(carboxylic acid silyl ester)s[J].China Plastics,2005(8). |
| |
| Authors: | HAN Nian-feng LIU Zong-lin WANG Qin XIA Yi-ran School of Chemistry and Chemical Engineering Shandong University Jinan China Shandong Medical Instrument Institute Jinan China |
| |
| Affiliation: | HAN Nian-feng 1, LIU Zong-lin 1, WANG Qin 2, XIA Yi-ran 1 1.School of Chemistry and Chemical Engineering,Shandong University,Jinan 250100,China, 2.Shandong Medical Instrument Institute,Jinan 250100,China |
| |
| Abstract: | Preparation methods and degradation behavior for poly(carboxylic acid silyl ester)s were reviewed. Main methods for the preparation of poly(carboxylic acid silyl ester)s, including transsilylation esterification of AA/BB comonorners, transsilylation esterification of AB monomers, hydrosilylation of AB monomers, and cross-dehydrocoupling-based polymerization were introduced and compared. Degradation mechanism and affecting factors of degradation rate were discussed in detail. Potential applications of poly(carboxylic acid silyl ester)sin biomedical field and environmental protection were prospected. |
| |
| Keywords: | poly(carboxylic acid silyl ester) synthesis method degradable behavior |
| 本文献已被 CNKI 等数据库收录！ |
|
