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Microstructure of reactively sputtered oxide diffusion barriers
Authors:E Kolawa  C W Nieh  F C T So  M -A Nicolet
Affiliation:(1) California Institute of Technology, 91125 Pasadena, CA;(2) Hewlett-Packard Co., 95131 San Jose, CA
Abstract:Molybdenum oxide (Mo1-x O x ) and ruthenium oxide (RuO2) films were prepared by rf reactive sputtering of Mo or Ru targets in an O2/Ar plasma. Both films exhibit metallic conductivities. The influence of the deposition parameters on the phase that forms and on the microstructure of Mo1-x O x and RuO2 films is reported. A phase transformation is observed in Mo1-x O x films subjected to heat treatment. The diffusion barrier performance of Mo1-x O x and RuO2 layers interposed between Al and Si is compared.
Keywords:Mo1-x            O            x                        RuO2            metallic films  microstructure
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