| 甲基丙烯酸甲酯/丙烯酸丁酯的无皂乳液共聚 |
| |
| 引用本文： | 熊金钰,陈梅杰.甲基丙烯酸甲酯/丙烯酸丁酯的无皂乳液共聚[J].胶体与聚合物,2011,29(4):160-161. |
| |
| 作者姓名： | 熊金钰 陈梅杰 |
| |
| 作者单位： | 安徽理工大学化学工程学院,安徽淮南,232001 |
| |
| 摘 要： | 以甲基丙烯酸甲酯(MMA)和丙烯酸丁酯(BA)为主要原料,过硫酸铵为引发剂,进行无皂乳液聚合.结果表明:在不添加乳化剂的情况下,当MMA/BA=1:1、引发剂用量为0.24%、反应温度为80℃、反应时间8.0h时,所得乳液最稳定,单体转化率为81.84%,此无皂乳液对牛皮纸的粘接性比常规乳液好.
|
| 关 键 词： | 甲基丙烯酸甲酯 丙烯酸丁酯 无皂乳液聚合 |
Emulsionfier-free Emusion Copolymerization of MMA/BA |
| |
| XIONG Jinyu,CHEN Meijie.Emulsionfier-free Emusion Copolymerization of MMA/BA[J].Chinese Journal of Colloid and Polymer,2011,29(4):160-161. |
| |
| Authors: | XIONG Jinyu CHEN Meijie |
| |
| Affiliation: | XIONG Jinyu,CHEN Meijie(School of Chemical Engineering,Anhui University of Science and Technology,Huainan,232001) |
| |
| Abstract: | The MMA/BA copolymer emulsion was prerared by emulsionfier-free emulsion polymerization using methyl methacrylate（MMA） and butyl acrylate（BA） as comonomers,APS as initiator.The result showed that the MMA/BA copolymer emulsionfier-free emusion has best stability when the mass ration of MMA：BA was 1：1 and mass fraction of the initiator was 0.24%.The monomer conversion ratio was 81.84% with the condition of the temperature 80℃ and the reaction time 8h. |
| |
| Keywords: | Methyl Methacrylate Butyl Acrylate Emulsifier-free Emulsion Polymerization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
