| 二茂铁磷钼钒杂多酸电荷转移配合物的合成、表征及催化性能 |
| |
| 引用本文： | 赵春艳,马荣华,杨万丽,邓国.二茂铁磷钼钒杂多酸电荷转移配合物的合成、表征及催化性能[J].化学试剂,2011,33(3):279-282. |
| |
| 作者姓名： | 赵春艳 马荣华 杨万丽 邓国 |
| |
| 作者单位： | 齐齐哈尔大学,化学与化学工程学院,黑龙江,齐齐哈尔,161006 |
| |
| 基金项目： | 黑龙江省省教育厅基金资助项目 |
| |
| 摘 要： | 以Keggin结构的钒取代的磷钼酸为电子受体,二茂铁为电子给体合成了3种二茂铁磷钼钒杂多酸电荷转移配合物Fe(C5H5)2]3HPMo11 VO40]·6H2O、Fe(C5H5)2]3 HPMo10V2O40]·3H2O和Fe(C5H5)2]3HPMo9V3O40]·8H2O,用元素分析、IR光谱、UV光谱...
|
| 关 键 词： | 二茂铁 磷钼钒杂多酸 电荷转移配合物 |
Synthesis,characterization and catalytic activity of the charge transfer salt between ferrocene and phosphomolybdate vanadium |
| |
| ZHAO Chun-yan,MA Rong-hua,YANG Wan-li,DENG Guo.Synthesis,characterization and catalytic activity of the charge transfer salt between ferrocene and phosphomolybdate vanadium[J].Chemical Reagents,2011,33(3):279-282. |
| |
| Authors: | ZHAO Chun-yan MA Rong-hua YANG Wan-li DENG Guo |
| |
| Affiliation: | ZHAO Chun-yan,MA Rong-hua,YANG Wan-li,DENG Guo(Department of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161006,China) |
| |
| Abstract: | Two new charge-transfer saltsFe(C5H5)2]3H-PMo11VO40]andFe(C5H5)2]3KPMo11VO40]have been prepared in aqueous from ferrocene and vanadate substituted molybdophosphoric with keggin structure.The samples were characterized by elemental analysis,IR,UV and XRD,The resules showed that charge transfer between ferrocene and polyoxometalate anion has taken place and formed charge-transfer sate,The polyoxometalate anion still remains its Keggin and Ferrocene structure in charge-transfer sate.Experiments on catalyti... |
| |
| Keywords: | ferrocene phosphomolybdate vanadium charge-transfer sate |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
