| 过渡金属离子核外电子排布对介孔M-TiO_2-SiO_2吸附剂吸附性能的影响 |
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| 引用本文： | 缪应纯,汤永裕,杨丽芬,韩福强,李贵军.过渡金属离子核外电子排布对介孔M-TiO_2-SiO_2吸附剂吸附性能的影响[J].曲靖师范学院学报,2011,30(3). |
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| 作者姓名： | 缪应纯 汤永裕 杨丽芬 韩福强 李贵军 |
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| 作者单位： | 曲靖师范学院化学化工学院,云南曲靖,655011 |
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| 基金项目： | 云南省教育厅科学研究基金项目(09Y0392); 曲靖师范学院科学研究基金项目(2009QN032),曲靖师范学院分析化学重点课程,曲靖师范学院资源与环境化学重点实验室 |
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| 摘 要： | 利用稻壳为模板和硅源合成Fe3+,Co2+,Ni2+,Cu2+,Zn2+,Cd2+,Ag+,Pb2+等8种过渡金属离子掺杂的M-TiO2-SiO2吸附剂,研究其在室温避光条件下对番红花T和龙胆紫染料水溶液吸附性能的差异.研究结果表明:掺杂第四周期过渡金属离子的M-TiO2-SiO2吸附剂的吸附性能随着过渡金属离子3d轨道电子数的增加,吸附性能呈现出先增大后减小的趋势;掺杂副族金属离子的M-TiO2-SiO2吸附剂的吸附性能随着金属离子主量子数的增大,吸附性能增大.
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| 关 键 词： | 稻壳 M-TiO2-SiO2 过渡金属离子 核外电子排布 吸附性能 |
Effect of Adsorptive Activity on Extranuclear Electronic Configuration in the Sorbent M-TiO_2-SiO_2 of Removal Dyes Using Rice Husks |
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| MiaoYingchun,Tang Yongyu,Yang Lifeng,Tan Fuqiang,Li Guijun.Effect of Adsorptive Activity on Extranuclear Electronic Configuration in the Sorbent M-TiO_2-SiO_2 of Removal Dyes Using Rice Husks[J].Journal of Qujing Normal College,2011,30(3). |
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| Authors: | MiaoYingchun Tang Yongyu Yang Lifeng Tan Fuqiang Li Guijun |
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| Affiliation: | MiaoYingchun,Tang Yongyu,Yang Lifeng,Tan Fuqiang,Li Guijun(School of Chemical and Engineering,Qujing Normal University,Qujing Yunnan 655011,P.R.China) |
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| Abstract: | The M-TiO2-SiO2(M:Fe,Co,Ni,Cu,Zn,Cd,Ag,Pb)were synthesized through rice husks as both silicon source and template and they were used for the absorption of removal dyes.The results indicated that M-TiO2-SiO2 exhibited higher absorption of removal dyes than that of P25,and the absorption yields of removal dyes were about 80% for gentian violet and safranine T.Furthermore,with atomic number increased,the M-TiO2-SiO2 absorption of removal dyes first increased,then decreased in the four cycle number metal.The Ni... |
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| Keywords: | rice husk M-TiO2-SiO2 extranuclear electronic configuration adsorptive activity |
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