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天然苯甲醛的合成方法的研究进展
引用本文:纪红兵,陈鸿雁,王乐夫.天然苯甲醛的合成方法的研究进展[J].精细化工,2010,27(6).
作者姓名:纪红兵  陈鸿雁  王乐夫
作者单位:1. 华南理工大学,化学与化工学院,广东,广州,510640
2. 中山大学,化学与化学工程学院,广东省低碳化学与过程节能重点实验室,广东,广州,510275
基金项目:国家自然科学基金,中山市产学研结合项目 
摘    要:天然苯甲醛是国际紧俏香料之一。综述了天然苯甲醛的几种合成方法:苦杏仁苷碱性水解法,肉桂油制备天然苯甲醛的方法,L-苯丙氨酸微生物法。重点介绍了由我国资源丰富的天然肉桂油制备天然苯甲醛的研究进展,主要有氧化法、碱性水解法以及近临界水法等,以期对高效提高天然肉桂油的附加值提供参考。

关 键 词:天然苯甲醛  苦杏仁苷  天然肉桂油  肉桂醛  L-苯丙氨酸  香料与香精
收稿时间:3/6/2010 12:00:00 AM
修稿时间:4/1/2010 12:00:00 AM

Advance in Synthesis of Natural Benzaldehyde
JI Hong-bing,CHEN Hong-yan and WANG Le-fu.Advance in Synthesis of Natural Benzaldehyde[J].Fine Chemicals,2010,27(6).
Authors:JI Hong-bing  CHEN Hong-yan and WANG Le-fu
Affiliation:School of Chemistry and Chemical Engineering, South China University of Technology,School of Chemistry and Chemical Engineering, South China University of Technology
Abstract:Natural benzaldehyde is one of short-supply international spice. In this paper, several synthetic methods of natural benzaldehyde are reviewed: hydrolysis of Laetrile; synthesis of cinnamon oil and biotransformation of L-phenylalanine. Preparation of natural benzaldehyde from natural cinnamon oil, which is rich in China, is introduced in detail, including oxidation, alkaline hydrolysis and NCW (near-critical water) method, with a view to provide guided information for increasing the added value of natural cinnamon oil.
Keywords:natural benzaldehyde  Laetrile  natural cinnamon oil  L-phenylalanine
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