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Fenton-铁氧体法处理含铜模拟废水的研究
引用本文:张彦,徐祺辉,孙尧,范凯霞,田敏,沈拥军.Fenton-铁氧体法处理含铜模拟废水的研究[J].电镀与环保,2017,37(3).
作者姓名:张彦  徐祺辉  孙尧  范凯霞  田敏  沈拥军
作者单位:南通大学化学化工学院,江苏南通,226019
摘    要:采用Fenton-铁氧体法处理含铜模拟废水。在pH值3.0、温度40℃、反应时间10 min、H_2O_20.60mL/L、FeSO_4·7H_2O 7.08g/L的条件下,Cu~(2+)的去除率达到92.88%,残余Cu~(2+)的质量浓度为3.56 mg/L。铁氧体法的最优工艺条件为:沉淀pH值10.0,反应时间15 min,温度30℃,FeSO_4·7H_2O 0.154g/L,FeCl_3·6H_2O 0.225g/L。在Fenton-铁氧体法的优化条件下,Cu~(2+)的去除率达到98.28%,残余Cu~(2+)的质量浓度为0.86mg/L,达到排放标准。

关 键 词:电镀废水  Fenton氧化  铁氧体法  Cu2+

Research on Treatment of Simulated Wastewater Containing Copper by Fenton-Ferrite
ZHANG Yan,XU Qi-hui,SUN Yao,FAN Kai-xia,TIAN Min,SHEN Yong-jun.Research on Treatment of Simulated Wastewater Containing Copper by Fenton-Ferrite[J].Electroplating & Pollution Control,2017,37(3).
Authors:ZHANG Yan  XU Qi-hui  SUN Yao  FAN Kai-xia  TIAN Min  SHEN Yong-jun
Abstract:Fenton-ferrite process was used to treat simulated wastewater containing copper.Under the conditions of pH value 3.0,temperature 40 ℃,reaction time 10 min,H2O2 0.60 mL/L and FeSO4 · 7H2O 7.08 g/L,the removal rate of Cu2+ reached to 92.88%,and the mass concentration of residual Cu2+ was 3.56 mg/L.The optimum process conditions of Fenton method were as follows:pH value 10.0,reaction time 15 min,temperature 30 ℃,FeSO4 · 7H2O 0.154 g/L,FeCl3 · 6H2O 0.225 g/L.Under these optimum conditions,the removal rate of Cu2+ reached to 98.28%,and the mass concentration of residual Cu2+ was 0.86 mg/L,indicating that meet the requirement of discharge standard.
Keywords:electroplating wastewater  Fenton oxidation  ferrite method  Cu2+
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