| 六（4-羟甲基苯氧基）环三膦腈的合成研究 |
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| 引用本文： | 马琴,姜月梅,胡敏奇,邵立东,段四美,毕韵梅.六（4-羟甲基苯氧基）环三膦腈的合成研究[J].广州化工,2011,39(5):69-71. |
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| 作者姓名： | 马琴 姜月梅 胡敏奇 邵立东 段四美 毕韵梅 |
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| 作者单位： | 云南师范大学化学化工学院,云南,昆明,650092 |
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| 基金项目： | 云南省大学生创新性实验计划，云南师范大学施源大学生科技创新基金 |
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| 摘 要： | 比较了合成星形聚合物原料-六（4-羟甲基苯氧基）环三膦腈的两条路线,并改进了较好路线的中间产物六（4-甲酰苯氧基）环三膦腈的合成条件。结果表明,以4-二甲氨基吡啶和三乙胺为缚酸剂,用4-羟基苯甲醛与六氯环三膦腈一锅煮反应,合成六（4-甲酰苯氧基）环三膦腈,再用NaBH4还原,是合成六（4-羟甲基苯氧基）环三膦腈的较好方法。
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| 关 键 词： | 六（4-羟甲基苯氧基）环三膦腈 合成路线 六（4-甲酰苯氧基）环三膦腈 一锅煮法 |
Study on Synthesis of Hexakis [4-(hydroxymethyl) phenoxyl]cyclotriphosphazene |
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| MA Qin,JIANG Yue-mei,HU Min-qi,SHAO Li-dong,DUAN Si-mei,BI Yun-mei.Study on Synthesis of Hexakis [4-(hydroxymethyl) phenoxyl]cyclotriphosphazene[J].GuangZhou Chemical Industry and Technology,2011,39(5):69-71. |
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| Authors: | MA Qin JIANG Yue-mei HU Min-qi SHAO Li-dong DUAN Si-mei BI Yun-mei |
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| Affiliation: | (College of Chemistry and Chemical Engineering,Yunnan Normal University,Yunnan Kunming 650092,China) |
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| Abstract: | Two systhesis methods of star polymers with hexakis 4-(hydroxymethyl)phenoxyl] cyclotriphosphazene as raw material were compared by experimental research.The synthetic condition of medial product hexakis 4-formylphenoxyl] cyclotriphosphazene in a better method was also improved.It was the better method to synthesizing hexakis 4-(hydroxymethyl) phenoxy] cyclotriphosphazene by the reaction of hexachlorocycltriphosphaneze with 4-hydroxybenzaldehyde in the presence of 4-dimethylaminopyridine and triethylamine as acid accertor and subsequent reduction of aldehyde groups to alcohol groups by using sodium borohydride. |
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| Keywords: | hexakis[4-(hydroxymethyl)phenoxyl] cyclotriphosphazene synthetic methods hexakis[4-formylphenoxyl] cyclotriphosphazene a pot synthesis |
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