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| 钨系列多金属氧酸哌啶配合物的合成 | |
| 引用本文： | 周端文,朱琳,张海淼,孙丽娜,吴元明.钨系列多金属氧酸哌啶配合物的合成[J].吉林化工学院学报,2008,25(2):1-3. |
| 作者姓名： | 周端文 朱琳 张海淼 孙丽娜 吴元明 |
| 作者单位： | 1. 吉林化工学院,化学与制药工程学院,吉林,吉林,132022 2. 吉林化工学院,分析测试中心,吉林,吉林,132022 3. 吉林农业大学,生命科学学院,吉林,长春,130118 |
| 摘 要： | 首次合成了2种新型有机一无机电荷转移配合物：（C5H10NH2）4SiW12O40，（C5H10NH2）4GeW12O40·并通过元素分析、红外光谱对新合成的化合物进行表征．红外数据表明，多阴离子仍保持原来的Keggin结构，其特征吸收峰有一定的红移或蓝移，说明哌啶分子与多阴离子之间有较强的相互作用． |
| 关 键 词： | 哌啶 多金属氧酸盐 有机/无机杂化 电荷转移配合物 |
| 文章编号： | 1007-2853(2008)02-0001-03 |
| 修稿时间： | 2008年1月9日 |
Synthesis of polyoxometalate complexes containing piperidine |
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| ZHOU Duan-wen,ZHU Lin,ZHANG Hai-miao,SUN Li-na,WU Yuan-ming.Synthesis of polyoxometalate complexes containing piperidine[J].Journal of Jilin Institute of Chemical Technology,2008,25(2):1-3. | |
| Authors: | ZHOU Duan-wen ZHU Lin ZHANG Hai-miao SUN Li-na WU Yuan-ming |
| Affiliation: | ZHOU Duan-wen, ZHU Lin, ZHANG Hai-miao, SUN Li-na, WU Yuan-ming ( 1. College of Chemical ＆ Pharmaceutical Engineering, Jilin Institute of Chemical Technology,Jilin City 132022, China; 2. Center of Analysis and Measurement, Jilin Institute of Chemical Technology, Jilin City 132022, China; 3. College of Life Science, Jilin Agricultural University,Changchnn 130118 ,China) |
| Abstract: | Two new organic/inorganic hybrid charge transfer salts(C5H10NH2)4SiW12O40 and(C5H10NH2)4GeW12O40 have been synthesized using conventional methods and characterized by elemental analysis and IR spectrum.The IR analysis shows that these compounds heterpolyanions still reserved their Keggin structure and their absorptions have more or less red shift or blue shift.It is the certificate of the strong interaction between the heterpolyanions and organic molecule. |
| Keywords: | piperdine polyoxometalate organic/inorganic hybrid charge-transfer complex |
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