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Luminescent properties of Ba3Gd(BO3)3:Eu^3+ phosphor for white LED applications
引用本文:周立亚,黄君丽,易灵红,龚孟濂,石建新.Luminescent properties of Ba3Gd(BO3)3:Eu^3+ phosphor for white LED applications[J].中国稀土学报(英文版),2009,27(1):54-57.
作者姓名:周立亚  黄君丽  易灵红  龚孟濂  石建新
作者单位:ZHOU Liya,HUANG Junli,YI Linghong(School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China);GONG Menglian,SHI Jianxin(School of Chemistry and Chemical Engineering Sun Yat-sen University Guangzhou 510275 China)  
基金项目:the Science Foundation of Guangxi Province,the Large-Scale Instrument of Guangxi Cooperates and Shares the Net Work,the Innovation Project of Guangxi Graduate Education 
摘    要:

关 键 词:白光LED  发光性能  荧光粉  应用  扫描电子显微镜  X射线衍射  Eu  粒子形态
收稿时间:8 April 2008

Luminescent properties of Ba3Gd(BO3) 3:Eu3+ phosphor for white LED applications
ZHOU Liya,HUANG Junli,YI Linghong,GONG Menglian,SHI Jianxin.Luminescent properties of Ba3Gd(BO3) 3:Eu3+ phosphor for white LED applications[J].Journal of Rare Earths,2009,27(1):54-57.
Authors:ZHOU Liya  HUANG Junli  YI Linghong  GONG Menglian  SHI Jianxin
Affiliation:ZHOU Liya, HUANG Junli, YI Linghong, GONG Menglian , Sill Jianxin(1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China; 2. School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China)
Abstract:Luminescent material Ba3Gd(BO3)3 doped with Eu3+ ion was prepared by high temperature solid-state method. The preparing conditions, luminescent properties, and particle morphology of Ba3Gd(BO3)3:Eu3 + phosphor were studied with X-ray diffraction (XRD), fluorescence spectroscopy, and scanning electron microscopy (SEM). The results obtained by XRD showed that pure phase of Ba3Gd(BO3)3 was obtained at 1000℃. Images from SEM displayed that the particles of Ba3Gd(BO3)3:Eu3+ phosphor had a spherical shape with an average diameter of about 200-400 nm. The luminescence spectra showed that Ba3Gd(BO3)3:Eu3+ phosphor was effectively excited by the near ultraviolet (UV) light (396 nm) and blue light (466 nm). The main emission peaks of Ba3Gd(BO3)3:Eu3+ phosphor were assigned to the supersensitive transition 5D0-7F2 (611 and 616 nm) of Eu3+ ion when samples were excited at 255 and 396 nm, respectively, and the luminescent intensity of Ba3Gd(BO3)3:Eu3+ at 611 and 616 nm reached to the maximum when the doped content of Eu3+ ion was 10mol.%. Therefore, this phosphor could be a promising red component for possible applications in the field of white LED.
Keywords:Ba3Gd(BO3)3  phosphor  luminescence  rare earths
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