Abstract: | The organic Rankine cycle(ORC) is an efficient power generation technology and has been widely used for renewable energy utilization and industrial waste heat recovery. Thermal stability is a significant property of ORC working fluids and is the primary limitation for working fluid selection and system design. This paper presents a review of the working fluid thermal stability for ORCs, including an analysis of the main theoretical method for thermal stability, a summary of the main experimental method for thermal stability, a summary of the decomposition experimental results for working fluids, and a discussion of the decomposition influence on ORC systems. Further research trends of thermal stability are also discussed in this paper. |