多孔材料在催化CO2与环氧化物环加成反应中的研究进展

以CO2为原料与环氧化物合成环状碳酸酯是实现CO2资源利用最为有效的途径之一，也是缓解温室效应的有效方式之一。在该反应中催化剂的选择至关重要，多孔材料由于具有相对密度低、强度高、比表面积大、稳定性好、合成方法多样等优点而被广泛应用于催化CO2环加成。重点综述了近年来无机多孔材料、多孔有机聚合物材料、金属有机骨架材料在催化CO2与环氧化物合成环状碳酸酯中的研究进展，介绍了各催化剂的优缺点并对未来多孔材料的发展进行了展望。

Research progress of porous materials in the cycloaddition of CO2 and epoxides

Using CO2 as raw material to synthesize cyclic carbonate with epoxide is one of the most effective ways to utilize CO2 resource, and it is also one of the effective ways to mitigate the greenhouse effect. It is believed that adopting appropriate catalyst is important in the reaction of CO2 with epoxide. Porous materials are widely used as catalyst of cycloaddition due to its low relative density, high strength, large specific surface area, good stability, and various synthetic methods. This paper focuses on the recent research progress of inorganic porous materials, porous organic polymer materials, and metal organic framework materials in the cycloaddition of CO2 and epoxides. The advantages and disadvantages of each catalyst are introduced.