| 苯选择性加氢钌催化剂的研究及应用进展 |
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| 引用本文： | 周伟,王克明,王红琴,安霓虹.苯选择性加氢钌催化剂的研究及应用进展[J].工业催化,2017,25(5):1-5. |
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| 作者姓名： | 周伟 王克明 王红琴 安霓虹 |
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| 作者单位： | 1.昆明贵金属研究所,贵研铂业股份有限公司 稀贵金属综合利用新技术国家重点实验室,云南 昆明 650106;2.福建天辰耀隆新材料有限公司,福建 福州 350309 |
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| 摘 要： | 苯选择性加氢钌催化剂广泛用于合成环己醇/酮,进而制备己内酰胺、己二酸、尼龙、聚酰胺等高附加值的精细化工产品。与传统工艺路线相比,苯选择性加氢技术路线具有安全环保和节能高效的特点,其中,催化反应体系是该技术路线的关键要素。重点概述了近年来苯选择性加氢钌催化剂的研究进展、工业应用现状及市场前景。
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| 关 键 词： | 有机化学工程 苯选择性加氢 钌催化剂 环己醇 环己酮 己内酰胺 己二酸 |
Advances in processes and ruthenium-based catalysts for benzene selective hydrogenation |
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| Zhou Wei,Wang Keming,Wang Hongqin,An Nihong.Advances in processes and ruthenium-based catalysts for benzene selective hydrogenation[J].Industrial Catalysis,2017,25(5):1-5. |
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| Authors: | Zhou Wei Wang Keming Wang Hongqin An Nihong |
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| Affiliation: | 1.State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,Sino-Platinum Metals Co.,Ltd.,Kunming Institute of Precious Metals,Kunming 650106,Yunnan,China;2.Fujian Tianchen Yaolong New Material Co.,Ltd.,Fuqing 350309,Fujian,China |
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| Abstract: | Ruthenium-based benzene selective hydrogenation catalysts have been widely used in synthesis of cyclohexanol/cyclohexanone and hence highly-valuable fine chemicals,such as caprolactam,adipic acid,nylon and polyamide.Compared with conventional technologies,benzene selective hydrogenation route features safety,low-emission,energy-saving and high efficiency.The catalytic system is the key to the route.Developments,application and prospects of Ru-based catalysts for benzene selective hydrogenation were reviewed. |
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| Keywords: | organic chemical engineering benzene selective hydrogenation ruthenium catalyst cyclohexanol cyclohexanone caprolactam adipic acid |
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