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Stability of hydrogenated nanodiamonds under extreme ultraviolet irradiation
Authors:YuV Butenko  PR Coxon  M Yeganeh  AC Brieva  K Liddell  VR Dhanak  L &#x;iller
Affiliation:

aSchool of Chemical Engineering and Advanced Materials, University of Newcastle upon Tyne, Newcastle upon Tyne, NE1 7RU, UK

bCCLRC, Daresbury Laboratory, Warrington, Cheshire, WA4 4AD, UK

cPhysics Department, University of Liverpool, Liverpool L69 3BX, UK

Abstract:It is generally accepted that diamond is resistant to a wide spectrum of electromagnetic radiation from the ultraviolet through to the soft X-ray range, which makes it very attractive for the fabrication of diamond-based photodetectors. However the effect of photon radiation on the diamond structure has not yet been examined. In the work presented here, photoelectron spectroscopy has been used to study the graphitization of nanodiamond crystallites exposed to extreme ultraviolet radiation. Under such irradiation, the surface hydrogen groups and graphite species are found to prevent graphitization. The mechanism of radiation-induced nanodiamond graphitization is discussed.
Keywords:Detectors  Nanoparticles  Radiation induced effects  Surface characterization
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