| 多反应体系热力学中的元素组成法(Ⅱ):剩余性质、混合变化性质及超额性质之间的关系 |
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| 引用本文： | 林金清,李浩然,韩世钧.多反应体系热力学中的元素组成法(Ⅱ):剩余性质、混合变化性质及超额性质之间的关系[J].中国化学工程学报,2002,10(4):464-468. |
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| 作者姓名： | 林金清 李浩然 韩世钧 |
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| 作者单位： | [1]CollegeofChemicalEngineering,HuaqiaoUniversity,Quanzhou362011,China [2]DepartmentofChemistry,ZhejiangUniversity,Hangzhou310027,China |
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| 基金项目： | Supported by the National Natural Science Foundation of China (No. 29976035) and the Natural Science Foundation of Fujian Province (No. B9810011). |
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| 摘 要： | Based on the concept of “element” and the fundamental thermodynamic principle,the relationships of the residual properties,the property changes of mixing,excess properties,fugacity coefficients and activity coefficients between the hypothetical solution of elemental species and the equilibrated solution of actual species were established.The hypothetical solution of elemental species provides a way of reducing the dimensionality of problem, simplifying the analysis and visualizing the phase behavior.
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| 关 键 词： | 元素组成 化学组成 热力学 相平衡 多反位体系 残留性能 |
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