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纤维素铜氨溶液的溶解性能及流变性能
引用本文:张须友,朱平,张林,董朝红,郑丽.纤维素铜氨溶液的溶解性能及流变性能[J].合成纤维工业,2012,35(3):28-30.
作者姓名:张须友  朱平  张林  董朝红  郑丽
作者单位:1. 青岛大学纤维新材料及现代纺织国家重点实验室培育基地,山东青岛,266071
2. 青岛大学纤维新材料及现代纺织国家重点实验室培育基地,山东青岛266071;武汉纺织大学新型纺织材料绿色加工及其功能化教育部重点实验室,湖北武汉430073
摘    要:研究了纤维素在铜氨溶液中不同溶解条件下的溶解特性,以及纤维素铜氨溶液的流变性能。结果表明:当溶解温度为-10℃,Cu2+浓度为1.4 mol/L,溶解时间1 h时,纤维素在铜氨溶液中有较大的溶解度;纤维素铜氨溶液为假塑性流体,其黏度随温度的升高而降低,随纤维素含量的升高而增大,当纤维素含量较高时,其黏度随温度的变化幅度较大。

关 键 词:纤维素  铜氨溶液  溶解  黏度  流变性能

Rheological properties and solubility of cellulose cuprammonium complex solution
Zhang Xuyou , Zhu Ping , Zhang Lin , Dong Zhaohong , Zheng Li.Rheological properties and solubility of cellulose cuprammonium complex solution[J].China Synthetic Fiber Industry,2012,35(3):28-30.
Authors:Zhang Xuyou  Zhu Ping  Zhang Lin  Dong Zhaohong  Zheng Li
Affiliation:1 (1.State Key Laboratory of New Fabric Material and Modern Textile,Qingdao University, Qingdao 266071;2.Key Laboratory of Green Processing and Functional Textiles of New Textile Materials of Ministry of Education,Wuhan Textile University,Wuhan 430073)
Abstract:The solubility of cellulose in cuprammonium complex solution was studied under different dissolution conditions,as was the rheological properties of cellulose cuprammonium complex solution.The results showed that the cellulose cuprammonium complex solution had relatively high solubility when the dissolution temperature was-10 ℃,Cu2+ concentration 1.4 mol/L,and dissolution time 1 h;the cellulose cuprammonium complex solution was pseudoplastic fluid,whose viscosity dropped with the increase of temperature and rose with the increase of cellulose content;and the viscosity changed considerably with the temperature as the cellulose content was relatively high.
Keywords:cellulose  cuprammonium complex solution  dissolution  viscosity  rheological properties
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