| 苯基异硫腈钴（I）配合物的合成与结构及性质 |
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| 引用本文： | 刘国湘,张新位,胡德荣.苯基异硫腈钴（I）配合物的合成与结构及性质[J].武汉化工学院学报,1996(1). |
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| 作者姓名： | 刘国湘 张新位 胡德荣 |
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| 作者单位： | 首都师范大学 |
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| 摘 要： | 本文报导了三－三苯基膦氧化钴（Ｉ）与过量的异硫氰酸苯酯反应，依据快原子轰击质谱（ＦＡＢ－ＭＳ），证实生成物的结构为四员钴杂环配合物。该配合物不稳定，容易脱硫，生成苯基异腈钴（Ⅱ）配合物。
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| 关 键 词： | Co（I）配合物 异硫氰酸苯酯 脱硫作用 |
Synthesis,Structure and Characterization of Phenyl Isothiocyanate Cobalt(I) Complexes |
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| Liu Guoxiang,Zhang Xinwei,Hu Derong.Synthesis,Structure and Characterization of Phenyl Isothiocyanate Cobalt(I) Complexes[J].Journal of Wuhan Institute of Chemical Technology,1996(1). |
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| Authors: | Liu Guoxiang Zhang Xinwei Hu Derong |
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| Affiliation: | Liu Guoxiang;Zhang Xinwei;Hu Derong |
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| Abstract: | The isonitriladithiocarbonimidat cobalt(I) complex is obtained by reaction of Co(I) Cl (pph3)3 with excessive phenyl isothiocyanate (PhNCS).Its structure has been determined by means of FABMS.It is 6-coordineted complex containing four-menbered cobalt (I) heterocycle ().The complex is unstabilized and the sulfur abstraction results in formation of phenyl isocyanide cobalt(I). |
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| Keywords: | Cobalt(I) complex Phenyl isothiocyanate Sulfur abstraction |
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