| 2,3-二羟基哌嗪与几种氨基化合物的缩合反应研究 |
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| 引用本文： | 陆明,吕春绪,魏运洋.2,3-二羟基哌嗪与几种氨基化合物的缩合反应研究[J].南京理工大学学报(自然科学版),1998(3). |
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| 作者姓名： | 陆明 吕春绪 魏运洋 |
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| 作者单位： | 南京理工大学化工学院 |
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| 摘 要： | 由乙二胺与乙二醛的缩合物２，３－二羟基哌嗪，分别与甲酰胺、脲和乙二胺反应，制得２，４，７，９，１１，１４－六氮杂三环［８，４，０，０３，８］十四烷六盐酸盐四水合物（１），２，５，７，９－四氮杂双环［４，３，０］壬－８－酮二盐酸盐－水合物（２）和２，５，７，１０－四氮杂双环［４，４，０］癸烷（３）。化合物１为未见文献报道的新化合物。化合物２的合成工艺条件优化后，反应得率与文献［１］相比有一定提高。化合物３的合成，由于将反应分为低温和高温两个缩合阶段，使反应得率提高到７７．５％。
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| 关 键 词： | 缩合反应，合成，工艺 高能量密度材料，氮杂环化合物 |
A Study on the Condensation Reaction of 2,3-bishydroxylpiperazine with Some Amino compounds |
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| Lu Ming,Lu Chunxu,Wei Yunyang.A Study on the Condensation Reaction of 2,3-bishydroxylpiperazine with Some Amino compounds[J].Journal of Nanjing University of Science and Technology(Nature Science),1998(3). |
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| Authors: | Lu Ming Lu Chunxu Wei Yunyang |
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| Abstract: | Hydrochloride of 2,4,7,9,11,14 hexazatricyclo8,4,0,0 3,8 ] tetradecane(1) and hydrochloride of 2,5,7,9 tetrazabicycls nonan 8 one(2) and 2,5,7,10 tetrazabicyclo decane(3) were synthesized via reaction of 2,3 bishydroxylpiperazine that is the condensation product of ethylenediamine and glyoxal with formamide,urea and ethylenediamine respectively.Compound 1 is a new compound that was not reported in literature.The yield of compound 2 is higher than that in literature (1) with the improvement of reaction condition.The yield of compound 3 is as high as 77.5%,because the condensation reaction of synthesising compound 3 is divided into low temperature and high temperature. |
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| Keywords: | condensation reactions synthesis technology high energy density material azacyclo compound |
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