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大型天然气净化厂硫磺回收加氢尾气深度脱硫技术研究及工业应用
引用本文:胡天友,王晓东,贾勇,范锐,何金龙,陈庆梅,李小云,杨超越.大型天然气净化厂硫磺回收加氢尾气深度脱硫技术研究及工业应用[J].石油与天然气化工,2018,47(4):1-5.
作者姓名:胡天友  王晓东  贾勇  范锐  何金龙  陈庆梅  李小云  杨超越
作者单位:中国石油西南油气田公司天然气研究院;中国石油西南油气田公司重庆天然气净化总厂;中国石油西南油气田公司气田开发管理部
基金项目:国家“十三五”重大科技专项“四川盆地大型碳酸盐岩气田开发示范工程”(2016ZX05052)
摘    要:针对硫磺回收加氢尾气脱硫溶剂在低压下脱硫效果不理想导致排放尾气中SO_2质量浓度较高的问题,研究开发出了CT8-26加氢尾气深度脱硫溶剂,并在遂宁龙王庙天然气净化厂尾气处理装置上得到工业应用。应用结果表明,在天然气净化厂气质条件下,可使脱硫后加氢尾气中的H2S质量浓度20mg/m~3,能显著降低排放尾气中的SO_2质量浓度。

关 键 词:加氢尾气  硫磺回收  深度脱除H2S溶剂  选择性脱硫  SO2减排
收稿时间:2018/1/15 0:00:00

Study and industrial application of deep desulfurization technology in hydrogenation tail gas treatment of sulfur recovery units in large scale natural gas purification plant
Hu Tianyou,Wang Xiaodong,Jia Yong,Fan Rui,He Jinlong,Chen Qingmei,Li Xiaoyun and Yang Chaoyue.Study and industrial application of deep desulfurization technology in hydrogenation tail gas treatment of sulfur recovery units in large scale natural gas purification plant[J].Chemical Engineering of Oil and Gas,2018,47(4):1-5.
Authors:Hu Tianyou  Wang Xiaodong  Jia Yong  Fan Rui  He Jinlong  Chen Qingmei  Li Xiaoyun and Yang Chaoyue
Affiliation:Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu, Sichuan, China,Chongqing Natural Gas Purification Plant General, PetroChina Southwest Oil & Gasfield Company, Chongqing, China,Chongqing Natural Gas Purification Plant General, PetroChina Southwest Oil & Gasfield Company, Chongqing, China,Department of Developing Management, PetroChina Southwest Oil & Gasfield Company, Chengdu, Sichuan, China,Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu, Sichuan, China,Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu, Sichuan, China,Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu, Sichuan, China and Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gasfield Company, Chengdu, Sichuan, China
Abstract:The effect of desulfurization solvent for hydrogenation tail gas of Claus sulfur recovery process under low pressure was unsatisfactory, which led to higher SO2 mass concentration in discharged tail gas. To deal with this problem, a new serial of hydrogenation tail gas deep desulfurization solvent CT8-26 was developed and applied on the tail gas treatment unit of Suining Longwangmiao Natural Gas Purification Plant. The results indicated that under the feed gas condition of natural gas purification plant, H2S mass concentration in desulfurized tail gas could be reduced below 20 mg/m3, and therefore the SO2 mass concentration in discharged tail gas would be reduced evidently.
Keywords:hydrogenation tail gas  sulfur recovery  H2S deep removal solvent  selective desulfurization  SO2 emission reduction
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