新一代制冷剂HFO-1234yf的热物性模型

基于Peng-Robinson通用状态方程,采用基团贡献原理以及多项式拟合方法,建立了符合精度要求的新型LGWP制冷剂HFO-1234yf的热物性模型,并对模型进行了验证,利用数学软件对模型进行编程求解,得到了较为全面的HFO-1234yf制冷剂的热物性数据。将HFO-1234yf制冷剂与R134a及R417A制冷剂的热物性能进行了对比,结果显示HFO-1234yf的饱和蒸汽压力与定压比热容和R134a的表现相似,二者的饱和蒸气压均低于R417A,HFO-1234yf制冷剂与R134a和R417A相比,其饱和状态焓值较低,这将导致HFO-1234y系统运行时的性能系数不高。该模型能为HFO-1234yf制冷剂在汽车空调以及固定式空调制冷设备上的应用提供理论依据。

Thermal Properties Model for the New Refrigerant HFO-1234yf

Based on Peng-Robinson general state equation, combined with group contribution principle and a polynomial method, the thermal state model of the new LGWP refrigerant HFO-1234yf was established and validated with required accuracy. By using the computer programming, the state models were solved by a mathematic software and a complete thermal properties of refrigerant were obtained. The thermal properties of HFO-1234yf were compared with R417A and R134a, and the results showed that the saturated vapor pressure and the specific heat capacity under constant pressure of HFO-1234yf has a similar performance with R134a. Both The saturated vapor pressure of both HFO-1234yf and R134a are lower than R417A, and the saturated state enthalpy of HFO-1234yf is lower than R417A, which would lead that the HFO-1234yf system can not have a higher performance coefficient. The models could act as a theoretical basis for the application of HFO-1234yf in automotive air conditioning and fixed refrigeration equipment.