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预分散溶剂萃取分离苯酚溶液的研究
引用本文:王运东,陈敏,徐丽莲,戴猷元.预分散溶剂萃取分离苯酚溶液的研究[J].中国化学工程学报,2000,8(2):103-107.
作者姓名:王运东  陈敏  徐丽莲  戴猷元
作者单位:DepartmentofChemicalEngineering,TsinghuaUniversity,Beijing100084,China
基金项目:Supported by the National Natural Science Foundation of China(No.29676021 and No.29836130)
摘    要:Predispersed solvent extraction (PDSE) is a new method for separating solutes from aqueous solution by solvent extraction and one which has shown promise for extraction from extremely dilute solution very efficient and very quick. The use of colloidal liquid aphrons in predispersed solvent extraction may ameliorate the problems such as emulsion formation, reduction of interracial mass transfer and low interfacial mass transfer areas in solvent extraction process. In present paper, colloidal liquid aphrons are successfully generated using kerosene as a solvent,tributyl phosphate(TBP) as an extractant, sodium dodecyl benzene sulphate(SDBS) as surfactant in aqueous phase and Tween-80 in oil phase. Extraction of phenol from dilute solution was studied by using colloidal liquid aphrons and colloidal gas aphrons in a semi-batch extraction column. It has been found that the PDSE process is more suitable for extraction of dilute solutions. It has also been discovered that the PDSE process has a great advantage over traditional single-stage extraction process.

关 键 词:预分散溶剂萃取  分离  苯酚  稀溶液  传质  胶状液体  胶状气体
修稿时间: 

Removal of Phenol from Dilute Solutions by Predispersed Solvent Extraction
WANG Yundong,CHEN Min,XU Lilian,DAI Youyuan.Removal of Phenol from Dilute Solutions by Predispersed Solvent Extraction[J].Chinese Journal of Chemical Engineering,2000,8(2):103-107.
Authors:WANG Yundong  CHEN Min  XU Lilian  DAI Youyuan
Affiliation:Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
Abstract:Predispersed solvent extraction (PDSE) is a new method for separating solutes from aqueous solution by solvent extraction and one which has shown promise for extraction from extremely dilute solution very efficient and very quick. The use of colloidal liquid aphrons in predispersed solvent extraction may ameliorate the problems such as emulsion formation, reduction of interfacial mass transfer and low interfacial mass transfer areas in solvent extraction process. In present paper, colloidal liquid aphrons are successfully generated using kerosene as a solvent, tributyl phosphate(TBP) as an extractant, sodium dodecyl benzene sulphate(SDBS) as surfactant in aqueous phase and Tween-80 in oil phase. Extraction of phenol from dilute solution was studied by using colloidal liquid aphrons and colloidal gas aphrons in a semi-batch extraction column. It has been found that the PDSE process is more suitable for extraction of dilute solutions. It has also been discovered that the PDSE process has a great advantage over traditional single-stage extraction process.
Keywords:colloidal liquid aphron  colloidal gas aphron  predispersed solvent extraction  
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