Modelling and experimental results of heat transfer in a metal hydride store during hydrogen charge and discharge

A numerical model for the transient hydrogen charge/discharge rates and thermal behaviour of metal hydride stores was developed and verified against experiments using a cylindrical reactor filled with AB₅-type metal hydride. The model assumes local thermal equilibrium between the gas and solid phases, and incorporates the pressure and temperature-dependent hydrogen reaction rates, as well as heat transfer in the porous metal hydride bed. The model was verified through experimental data. The experiments were performed using a unit with hydrogen storage capacity of 130 Nl H₂; the store was submerged in an isothermal water bath. Experiments at different water bath temperatures and charge/discharge hydrogen pressures indicated a relation between charge/discharge time and these parameters. The reactor's ability to deliver a constant hydrogen flow at different water bath temperatures was experimentally investigated. During simulations it was found that the model applied is sensitive to perturbations of some of its parameters; activation energy of absorption, effective conductivity and heat of reaction were found to be the most important ones. The charge and discharge performances of the store are controlled by the reaction rate in the first half-part of the H absorption/desorption experiments and by a heat transfer in the second half-part of charge/discharge.