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以二吡啶胺为配体的新型钴配合物的合成及结构
引用本文:李丽,程媛媛,邓元.以二吡啶胺为配体的新型钴配合物的合成及结构[J].广东化工,2014(2):36-37.
作者姓名:李丽  程媛媛  邓元
作者单位:[1]济宁市环保局商新区分局,山东济宁272000 [2]杭州师范大学有机硅化学及材料技术教育部重点实验室,浙江杭州311121
摘    要:以2,2’-二吡啶胺(Hdpa)和对氨基苯甲酸钠(PABA为4-氨基苯甲酸阴离子)为原料,和氯化钴反应合成了一种新型的钴配合物Co(Hdpa)2(PABA)]Cl(CH3OH),并通过扩散法得到了该配合物的单晶。通过单晶衍射、元素分析、红外光谱、质谱(ESI)对该配合物进行了结构表征。晶体结构表明:该配合物为阴离子-阳离子型化合物。

关 键 词:钴配合物  晶体结构  阴阳离子配合物

Study on the Synthesis,Crystal Structure for a Novel Cobalt Complex with Dipyridylamine Ligands
Li LiI,Cheng Yuanyuan,Deng Yuan.Study on the Synthesis,Crystal Structure for a Novel Cobalt Complex with Dipyridylamine Ligands[J].Guangdong Chemical Industry,2014(2):36-37.
Authors:Li LiI  Cheng Yuanyuan  Deng Yuan
Affiliation:2 (1. High-tech Industrial Department Zone Branch of Jining Environmental Protection Bureau, Jining 272000: 2. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou 311121, China)
Abstract:A novel cobalt complex with the formula of Co(Hdpa)2(PABA)]CI(CH3OH)(where Hdpa is 2,2'-dipyridylamine, PABA is 4-aminobenzoic acid anion) were synthesized and cbaracterized by elemental analysis, IR, MS(ESI) and single crystal X-ray diffraction analysis. We also obtained the crystal through difthsion method. Single crystal structure reveals that the complex was a cation-anionic complex.
Keywords:cobalt complex: crystal structure: cation-anioniccomplex
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