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Using a molten organic conducting material to infiltrate a nanoporous semiconductor film and its use in solid-state dye-sensitized solar cells
Authors:Kristofer Fredin  Erik MJ Johansson  Tobias Blom  Maria Hedlund  Stefan Plogmaker  Hans Siegbahn  Klaus Leifer  Håkan Rensmo
Affiliation:Department of Physics and Materials Science, Uppsala University, Box 530, SE-751 21 Uppsala, Sweden;MAX-lab, Lund University, Ole Römers väg 1, SE-223 63 Lund, Sweden;Department of Chemical Physics, Lund University, Box 124, SE-221 00 Lund, Sweden;Department of Engineering Sciences, Uppsala University, Box 534, SE-751 21 Uppsala, Sweden;Department of Physics and Materials Science, Uppsala University, Box 530, SE-751 21 Uppsala, Sweden;Department of Engineering Sciences, Uppsala University, Box 534, SE-751 21 Uppsala, Sweden;Department of Physics and Materials Science, Uppsala University, Box 530, SE-751 21 Uppsala, Sweden
Abstract:We describe a method to fill thin films of nanoporous TiO2 with solid organic hole-conducting materials and demonstrate the procedure specifically for use in the preparation of dye-sensitized solar cells. Cross-sections of the films were investigated by scanning electron microscopy and it was observed that a hot molten organic material fills pores that are 10 μm below the surface of the film. We characterized the incident photon to current conversion efficiency properties of the solid TiO2/organic dye/organic hole-conductor heterojunctions and the spectra show that the dye is still active after the melting process.
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