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During the ECM process, the metal workpiece is dissolved and turns into sludge which contaminates the electrolyte. To realize precise ECM with high cost-effectiveness, an electrolyte treatment system which can realize reuse of the electrolyte and maintain the electrolyte quality constant is significantly important and essential. Especially, in the ECM of alloys containing a certain level of chromium, it is very likely chromium dissolves to the toxic carcinogen Cr(VI). Therefore, an electrolyte filtration system is required for removing not only the sludge but also residual toxic ions in the electrolyte for health and environment conservation reasons. In this study, activated carbon and scrap iron, which are low cost and easily available materials, were newly utilized to reduce and remove toxic Cr(VI) ions. Experiments clarified that use of activated carbon has no influence on the machining ability of NaNO3 aqueous solution serving as the electrolyte. By adjusting the pH of the electrolyte to acidic, activated carbon can remove Cr(VI) from the NaNO3 aqueous solution electrolyte to a concentration of less than 0.1 mg/L. On the other hand, scrap iron generated from metal cutting processes can be used to reduce Cr(VI) to non-toxic Cr(III). By mixing HNO3 into the electrolyte solution, the reduction efficiency of scrap iron on Cr(VI) improves significantly. 相似文献
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废铁屑还原软锰矿制备高纯硫酸锰工艺研究 总被引:1,自引:0,他引:1
研究了采用废铁屑作为还原剂,在稀硫酸介质中湿法还原软锰矿制备硫酸锰的工艺过程。通过单因素实验确定最佳工艺参数,结果表明:当Fe/MnO2的摩尔比为0.78∶1,H2SO4/MnO2的摩尔比为2.1∶1,反应温度50℃,反应时间80 min时,锰的浸出率在95%以上。加入碳酸钙中和调节溶液pH值至5~6,使溶液中的铁、铝等杂质离子水解为氢氧化铁、氢氧化铝等沉淀除去,加入硫化钡使浸出溶液中的重金属离子以硫化物沉淀除去,减压过滤得到硫酸锰粗滤液,向粗滤液中加入二氟化锰使溶液中的Ca2+、Mg2+等离子生成氟化物沉淀,然后溶液经过静置过滤得到硫酸锰净化液,滤液经浓缩、结晶制备硫酸锰产品。经检测产品纯度在99%以上,杂质含量低于国家标准。 相似文献
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随着国家对环境方面的要求不断提高和企业对环保的重视,废钢加工处理过程中二次污染的防治问题逐渐成为物流分公司急需解决的重要问题,为了对废钢加工处理过程中的二次污染起到有效防治,为攀长特灾后重建废钢的合理环保利用提供一定的技术支撑,本文重点分析了废钢铁加工处理过程中二次污染的表现形式和有效防治途径,并提出了相应防治办法,以便为攀长特的二次创业提供更优质的废钢资源。 相似文献
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Tires exhibit different kinetic behaviors when pyrolyzed under different heating rates. A new algorithm has been developed to investigate pyrolysis behavior of scrap tires. The algorithm includes heat and mass transfer equations to account for the different extents of thermal lag as the tire is heated at different heating rates. The algorithm uses an iterative approach to fit model equations to experimental data to obtain quantitative values of kinetic parameters. These parameters describe the pyrolysis process well, with good agreement (r2 > 0.96) between the model and experimental data when the model is applied to three different brands of automobile tires heated under five different heating rates in a pure nitrogen atmosphere. The model agrees with other researchers’ results that frequencies factors increased and time constants decreased with increasing heating rates. The model also shows the change in the behavior of individual tire components when the heating rates are increased above 30 K min−1. This result indicates that heating rates, rather than temperature, can significantly affect pyrolysis reactions. This algorithm is simple in structure and yet accurate in describing tire pyrolysis under a wide range of heating rates (10–50 K min−1). It improves our understanding of the tire pyrolysis process by showing the relationship between the heating rate and the many components in a tire that depolymerize as parallel reactions. 相似文献
7.
《Machining Science and Technology》2013,17(2):193-210
Abstract The wear of tool blades for cost-effective scrap tire shredding is investigated. Rotary disk cutters are widely used for cutting scrap tires into small pieces. The hard, wear-resistant tool blades mounted on the periphery of disk cutters maintain a narrow gap between blades and generate the cutting action. The kinematics of the relative motion of two adjacent disk cutters is derived to model the overlap region on blades during cutting. The model predictions match well with the actual shapes of the worn regions on used tool blades. The wear of tool blades made of AISI D2 and CRU-WEAR (CW) tool steels for scrap tire shredding is evaluated. A coordinate measurement machine was used to measure the tool wear. The wear on the blade surface is not uniform. Regions with high wear rate are explained using the kinematics analysis. The CW blades show a lower wear rate, about half of that of D2 blades, and a potential choice for cost savings. 相似文献
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Seismic base isolation using low-cost Scrap Tire Pads (STP) 总被引:1,自引:0,他引:1
This paper focuses on the experimental studies conducted on the development of no-cost seismic base isolation pads using scrap
automobile tire pads (STP). The mechanical and dynamic properties of STP specimens made from different tire brands, with different
number of layers, and orientations are evaluated experimentally. The tests are conducted using (a) axial compression tests,
(b) lumped mass small displacement free vibration, and (c) large displacement (inclined plate and reverse-cyclic) static shear
tests. The results of these STP tests are compared among themselves and against a commercially available laminated rubber
bearing specimen. A general relationship has been proposed which formulates the stiffness differences between the two principal
directions of rectangular pads. The paper includes three hypothetical design applications for the use of STPs.
STPs are prepared by placing 18 cm × 20 cm cut tread sections layers of car tires on top each other. Larger size STPs can
also be formed by placing longer strips of tread sections (integer multiples of tread width) side by side in alternating direction
layers or using a woven structure. Test results have shown that the friction between tire layers is sufficient to keep layers
intact. Although STP application cannot eliminate foundation-basement structural requirements, it presents advantages such
as low-technology no-cost pad, weight reduction, ease of handling, simple shear stiffness adjustment by changing the number
of layers, and environmental benefits by recycling scrap tires. 相似文献