The effect of salinity and temperature on electromagnetic wave attenuation in brine

Ice slurries are typically formed from an aqueous solution of water and salt (NaCl) at 5% salinity. Ice pigs, used in many industry areas, are taken from a bulk ice slurry and used to clear waste or recover product from pipes. Ice fraction is a key property of an ice slurry, since it determines it's ‘thickness’ and therefore cleaning capacity. Electromagnetic wave interrogation has been shown to accurately predict an ice fraction to within an error of ±1.2%. The largest remaining process error comes from inherent salinity variation, which affects the electromagnetic wave attenuation significantly. Increasing electromagnetic wave attenuation with increasing salinity and the effect of temperature, shown to also increase attenuation, is quantified. Calibration methods are proposed, aiming to eliminate the unwanted effect of varying salinity. Analysis on multiple samples showed a 16% reduction in average error, and 9% reduction in maximum error when the calibration method was applied.     

1000 ton per day ice plant for underground cooling at Harmony gold mine

Up to now all refrigeration plants used for mine cooling have used chilled water. When these refrigeration plants are situated on the surface, large quantities of water must be sent into the mine and pumped back to the surface again. It was suggested that a viable and economic alternative was to make ice on the surface and send this into the mine to reduce the quantity of water required. This Paper describes the world's first very large ice plant used for mine cooling. Ice from this plant is used to cool hot water originating at an underground fissure, and, in addition, provides cooling in the mine.     

Performance analysis on the liquid-ice thermal storage system for optimum operation

For the purpose of determining the optimum operation condition of liquid-ice thermal storage system, the performance analysis has been carried out. The target system was consisted of refrigerator, its auxiliary devices, liquid-ice production device, piping system, and thermal load section. The system performances were widely investigated analytically for the variety of operation conditions including the cycle performance of a refrigerator. The optimum operation condition of the liquid-ice thermal storage system from the viewpoint of coefficient of performance and the performance of heat release were discussed.     

Continuous formation of slurry ice by cooling water–oil emulsion in a tube

Water-silicone oil emulsion with an additive, (C₂H₅O)₃SiC₃H₆NH₂, was examined as a heat storage material. A spiral tube used as a heat exchanger was immersed in a low temperature bath and the emulsion was circulated in the tube to make ice continuously. Ice was separated from the ice–liquid suspension in an outlet tank. The amount of formed ice, the temperatures of the inlet and the outlet of the heat exchanger, and the temperatures in the tube wall were measured and the overall heat transfer coefficient and the heat flux through the tube were calculated. Experiments were carried out, varying the flow rate, the temperature of cooling brine, and the thickness of tube wall. The condition under which slurry ice was formed continuously without adhesion of ice to the cooling wall was clarified. Though decrease in the thermal resistance of the tube increased the rate of ice formation or raised the brine temperature, it narrowed the range of the flow rate and of the brine temperature in which slurry ice was formed continuously.     

Simple mathematical model for predicting the transient behaviour of an ice-bank system

The time-variable performance of a Refrigerant 22 ice-bank system was simulated by a dynamic model which was derived by assuming that heat transfer was always the limiting process, and which thus ignored hydrodynamic processes. The model comprised four ordinary differential equations describing the position of the ice front, the water temperature, and the refrigerant evaporation and condensation temperatures, each of which was derived by energy balance, plus a number of algebraic equations. Measured plant performance was accurately predicted except immediately after start-up, and in circumstances in which the assumption that the dynamics of refrigerant flow did not exert any controlling influence on the overall process dynamics was inadequate (for example, when the thermostatic expansion valve operation becomes unstable). The model requires only data that should be readily available or can be easily estimated, and thus it is suitable for analyses in the design of ice bank systems to handle time-varying conditions. Simple dynamic models ignoring hydrodynamics can be adequate in circumstances where the main source of variation arises beyond the refrigeration circuit itself.     

Study on high performance ice slurry formed by cooling emulsion in ice storage (discussion on adaptability of emulsion to thermal storage material)

This study focuses on an emulsion as a new thermal storage material for ice storage. Two types of emulsions were formed using an oil–water mixture with a small amount of additive. A silicone, light and lump oils were used. The water contents of the emulsions were 70, 80 and 90%. The additive was an amino group modified silicone oil. No depression of freezing point was observed for the emulsions because of their hydrophobic properties. In order to determine the structure of the emulsions, their electrical resistances were measured. Moreover, components of the liquids separating from the emulsions were analyzed. The results indicated that one emulsion was a W/O type emulsion, while the other was an O/W type. Finally, adaptability of the two emulsions to ice storage was discussed, it was concluded that a high performance ice slurry could be formed by the W/O type emulsion.     

Continuous ice slurry formation by using W/O emulsion with higher water content

A W/O (water-in-oil) emulsion was made from a water–lamp oil mixture with higher water content and a small amount of an additive of amino group-modified silicone oil, and the emulsion could be changed into an ice slurry by cooling with stirring. By using a new continuous ice formation system proposed by one of the authors of this paper, the ice slurry could be formed continuously and stably in an ice formation vessel made of stainless steel. From the experimental results, the conditions were clarified for realizing continuous ice formation for 10 h without ice adhesion to the cooling wall. Moreover, in order to propagate supercooling dissolution of the emulsion effectively and to decrease viscosity in the ice slurry, voltages were applied to the emulsion and ice slurry formed, respectively, and it was clarified that the voltage impression was effective for both.     

Formation of high performance ice slurry by W/O emulsion in ice storage (effective method to propagate supercooling dissolution)

This study focused ice slurry formation in an ice storage system using W/O emulsions with 70 and 80% water contents. Emulsions consisted of a silicone oil–water mixture with a small amount of amino-group-modified silicone oil additive. Ice slurry was formed by cooling the emulsion without ice adhesion to the cooling wall, as water in the emulsion did not directly contact the cooling wall. As the structure of W/O emulsion slowed the propagation rate of supercooling dissolution, voltage and ultrasonic wave were applied to the W/O emulsion to propagate dissolution more quickly and decrease maximum supercooling degree, respectively. Thus, the effects of voltage and ultrasonic wave applications on propagation rate were clarified.     

Evaluation of the cooling performance of a consolidated expanded graphite–calcium chloride reactive bed for chemisorption icemaker

The cooling performance of a consolidated composite reactive bed made from expanded graphite impregnated with CaCl₂ was experimentally assessed under different evaporation and heat sink temperatures. The compound presented a specific cooling power (SCP) higher than 1000 W kg_Salt⁻¹ at several studied conditions. The calculated coefficient of performance (COP) was about 0.35 when the amount of refrigerant consumed in the reaction was 0.80 kg kg_Salt⁻¹. Both SCP and COP changed with the cycle time, and thus, with the degree of the reaction. The synthesis time to maximise the SCP, under any studied condition, was about 5 min, and the absorbed quantity greatly varied among the different operation conditions. When compared to the time necessary to obtain an absorbed amount of 0.80 kg kg_Salt⁻¹, the synthesis time of 5 min could improve the SCP in about 15–68%, however, COP would be deployed in about 14–50%.     

Solid fraction modelling for CO2 and CO2–THF hydrate slurries used as secondary refrigerants

In the present paper, the suitability of hydrate slurries in secondary refrigeration was investigated by the means of a new hydrate solid-fraction model. Considering the high melting enthalpy of CO₂-containing hydrates, slurries presenting high hydrate solid fractions can carry sufficient latent heat to be useful for a two-phase secondary-refrigerant application. The model presented in this paper allowed to calculate the solid fraction of CO₂ and CO₂–THF hydrate from thermodynamic conditions of pressure and temperature. Contrary to a previous work on single CO₂ hydrates in a closed system, the present model can take into account hydrate mixture and is well adapted to additional CO₂ injections (opened system). By relying on the hydrate-conversion model results, the study of hydrates in suspension in a carrying liquid was also studied in an experimental loop and was based on a formation process by CO₂ injection in a cooled aqueous solution.