全文获取类型
收费全文 | 172篇 |
免费 | 29篇 |
国内免费 | 8篇 |
学科分类
工业技术 | 209篇 |
出版年
2023年 | 3篇 |
2022年 | 6篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 10篇 |
2017年 | 8篇 |
2016年 | 14篇 |
2015年 | 8篇 |
2014年 | 2篇 |
2013年 | 8篇 |
2012年 | 7篇 |
2011年 | 9篇 |
2010年 | 12篇 |
2009年 | 11篇 |
2008年 | 10篇 |
2007年 | 7篇 |
2006年 | 12篇 |
2005年 | 5篇 |
2004年 | 10篇 |
2003年 | 4篇 |
2002年 | 6篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 1篇 |
1998年 | 6篇 |
1997年 | 1篇 |
1996年 | 7篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1985年 | 2篇 |
1975年 | 1篇 |
排序方式: 共有209条查询结果,搜索用时 15 毫秒
1.
针对芳香硝基化合物的催化选择性加氢反应,开发可替代贵金属催化剂的低成本、高效非贵金属催化剂,对于芳香胺类化合物的绿色生产具有重要意义。利用简易、可规模化的制备方法,以镍—2,5-吡啶二羧酸金属有机框架为前驱体,热解制备了氮掺杂石墨碳包覆镍纳米催化材料(Ni@CN)。采用X射线衍射、扫描电镜、透射电镜、元素分析、N2吸脱附等检测手段对Ni@CN的物化性质进行了表征,并对其催化性能进行了评价。结果表明,Ni@CN可在温和条件下(85℃,1.0 MPa H2)高效加氢含取代官能团的芳香硝基化合物生成对应的芳香胺类化合物。对比试验表明,镍纳米颗粒是Ni@CN的加氢活性中心,而石墨碳壳的存在有利于优先吸附硝基官能团。此外,进一步考察了Ni@CN的循环使用性能以及抗硫化物中毒的特性。 相似文献
2.
3.
Plastic encapsulated microcircuits (PEMs) are increasingly being used in applications requiring operation at temperatures lower than the manufacturer’s recommended minimum temperature, which is 0°C for commercial grade components and −40°C for industrial and automotive grade components. To characterize the susceptibility of PEMs to delamination at these extreme low temperatures, packages with different geometries, encapsulated in both biphenyl and novolac molding compounds, were subjected to up to 500 thermal cycles with minimum temperatures in the range −40 to −65°C in both the moisture saturated and baked conditions. Scanning acoustic microscopy revealed there was a negligible increase in delamination at the die-to-encapsulant interface after thermal cycling for the 84 lead PQFPs encapsulated in novolac and for both 84 lead PQFPs and 14 lead PDIPs encapsulated in biphenyl molding compound. Only the 14 lead novolac PDIPs exhibited increased delamination. Moisture exposure had a significant effect on the creation of additional delamination. 相似文献
4.
新型包膜尿素的制备及其特性的研究 总被引:2,自引:0,他引:2
以桐油为主要成膜物质制备新型包膜尿素。研究结果表明,包膜后尿素颗粒的粒径分布更加均匀,有外密封层时可在包膜尿素表面形成连续致密的包膜,包膜尿素因之获得逐步释放特性。使用溶解率和无土柱淋溶率可以评价包膜尿素的养份释放特性。 相似文献
5.
Hierarchical 3D Cobalt‐Doped Fe3O4 Nanospheres@NG Hybrid as an Advanced Anode Material for High‐Performance Asymmetric Supercapacitors 下载免费PDF全文
Meng Guo Jayaraman Balamurugan Xuyang Li Nam Hoon Kim Joong Hee Lee 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(33)
Hierarchical nanostructure, high electrical conductivity, extraordinary specific surface area, and unique porous architecture are essential properties in energy storage and conversion studies. A new type of hierarchical 3D cobalt encapsulated Fe3O4 nanosphere is successfully developed on N‐graphene sheet (Co?Fe3O4 NS@NG) hybrid with unique nanostructure by simple, scalable, and efficient solvothermal technique. When applied as an electrode material for supercapacitors, hierarchical Co?Fe3O4 NS@NG hybrid shows an ultrahigh specific capacitance (775 F g?1 at a current density of 1 A g?1) with exceptional rate capability (475 F g?1 at current density of 50 A g?1), and admirable cycling performance (97.1% capacitance retention after 10 000 cycles). Furthermore, the fabricated Co?Fe3O4 NS@NG//CoMnO3@NG asymmetric supercapacitor (ASC) device exhibits a high energy density of 89.1 Wh kg?1 at power density of 0.901 kW kg?1, and outstanding cycling performance (89.3% capacitance retention after 10 000 cycles). Such eminent electrochemical properties of the Co?Fe3O4 NS@NG are due to the high electrical conductivity, ultrahigh surface area, and unique porous architecture. This research first proposes hierarchical Co?Fe3O4 NS@NG hybrid as an ultrafast charge?discharge anode material for the ASC device, that holds great potential for the development of high‐performance energy storage devices. 相似文献
6.
纳米改性氢氧化铝与包覆红磷协效阻燃PBT的研究 总被引:2,自引:0,他引:2
以纳米改性氢氧化铝(CG-ATH)与包覆红磷(RP)为无卤阻燃剂,研究其对聚对苯二甲酸丁二醇酯(PBT)的阻燃性能和力学性能的影响。首先探讨了包覆红磷的添加量对PBT阻燃性能和力学性能的影响,然后固定包覆红磷用量,考察纳米CG-ATH的添加量对PBT/RP复合体系的阻燃性能和力学性能的影响。实验结果表明,纳米CG-ATH和包覆红磷能协效阻燃PBT复合体系,在包覆红磷添加量为10phr,纳米CG-ATH为20 phr时,PBT复合材料的氧指数从21%提高到30%,达到V-0级;复合材料的拉伸强度为57.0 M Pa,冲击强度为3.03 kJ/m2,断裂伸长率为5.79%,表明该PBT复合体系具有优良的阻燃性能和力学性能。 相似文献
7.
8.
9.
Structural and optical behavior of electrodeposited black chrome‐graphite encapsulated FeCo nanoparticles composite coatings 下载免费PDF全文
Black chrome‐graphite encapsulated FeCo nanoparticles (BC‐GEFeCo NPs) composite coatings were electrodeposited on substrates such as stainless steel, Cu, and Ni‐coated Cu. The major content of the deposited film is contributed by Cr, Fe‐Cr, Fe2AlCr, and FeCr0.29Ni0.16C0.06 as deduced from X‐ray diffraction. The root‐mean‐square roughness value of black chrome on Ni‐coated Cu employing PbSb anode is measured by atomic force microscopy (nanoindentation) studies as 57.176 nm, which is in satisfactory agreement with the literature value of 53.83 nm. With the addition of GEFeCo Nps, the root‐mean‐square roughness value for BC‐GEFeCo composite coatings on Ni‐coated Cu increases approximately 6.1 times that of black chrome surface. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
10.
Dong‐Won Lee Won‐Ju Cho Jun‐Kwang Song Oh‐Yun Kwon Won‐Hee Lee Chi‐Hong Park Kyung‐Eun Park Heesoo Lee Yong‐Nam Kim 《Progress in Photovoltaics: Research and Applications》2015,23(7):829-837
High‐temperature‐induced and humidity‐induced degradation behaviors were investigated through the failure analysis of encapsulated Cu(In,Ga)Se2 (CIGS) modules and non‐encapsulated CIGS cells. After being exposed to high temperature (85 °C) for 1000 h, the efficiency loss of CIGS modules and the resistivities of the aluminum‐doped zinc oxide (AZO) layer, CIGS layer, and Mo layer were slightly increased. After damp heat (DH) testing (85 °C/85% RH), the efficiency of some modules decreased significantly accompanied by discoloration, and in these areas, the resistivity of the AZO layers increased markedly. The causes of degradation of CIGS cells after high temperature and DH tests were suggested through X‐ray photoelectron spectroscopy analysis. The high‐temperature‐induced degradation behaviors were revealed to be increases in series resistance of the CIGS cells, due to the adsorption of oxygen on the AZO, CIGS, and Mo layers. The degradation behavior after DH (85 °C/85% RH) exposure was caused by the adsorption of oxygen, as well as the generation of Zn(OH)2 due to water molecules. In particular, the humidity‐induced degradation behavior in discolored CIGS modules was ascribed to the generation of Zn(OH)2 and carboxylic acids in the AZO layer, due to a chemical reaction between the AZO, ethylene‐vinyl acetate copolymer, and water. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献