全文获取类型
收费全文 | 3707篇 |
免费 | 243篇 |
国内免费 | 235篇 |
学科分类
工业技术 | 4185篇 |
出版年
2024年 | 4篇 |
2023年 | 38篇 |
2022年 | 57篇 |
2021年 | 89篇 |
2020年 | 97篇 |
2019年 | 85篇 |
2018年 | 72篇 |
2017年 | 119篇 |
2016年 | 112篇 |
2015年 | 122篇 |
2014年 | 170篇 |
2013年 | 196篇 |
2012年 | 247篇 |
2011年 | 257篇 |
2010年 | 203篇 |
2009年 | 211篇 |
2008年 | 218篇 |
2007年 | 254篇 |
2006年 | 246篇 |
2005年 | 202篇 |
2004年 | 185篇 |
2003年 | 170篇 |
2002年 | 140篇 |
2001年 | 89篇 |
2000年 | 81篇 |
1999年 | 92篇 |
1998年 | 70篇 |
1997年 | 54篇 |
1996年 | 53篇 |
1995年 | 39篇 |
1994年 | 46篇 |
1993年 | 28篇 |
1992年 | 25篇 |
1991年 | 19篇 |
1990年 | 23篇 |
1989年 | 16篇 |
1988年 | 7篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 4篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有4185条查询结果,搜索用时 78 毫秒
1.
为了探索三维石墨烯-碳纳米管(G-CNTs)/水泥净浆的压敏性能,采用四电极法研究了荷载作用下GCNTs/水泥净浆的电阻率变化,并分析不同G-CNTs掺量、加载幅度、加载速度以及恒定荷载对电阻率变化的影响。研究表明:随着G-CNTs掺量的增加,电阻率呈先减小后稳定的变化趋势,在G-CNTs掺量由0.2wt%增加至1.6wt%时,电阻率下降51.8%;电阻率与温度呈负相关;G-CNTs掺量高于0.8wt%时可以显著提高水泥净浆的压敏性能,且电阻率变化率与应力应变有明显的对应关系,1.2wt%G-CNTs掺量下试件的应力灵敏系数和应变灵敏系数分别为2.3%/MPa和291;G-CNTs/水泥净浆电阻率变化率幅值随着加载幅度增大而相应增加,其电阻率变化率曲线在不同加载速度以及恒定荷载作用下均与应力-应变曲线一一对应,具有良好的压敏特性。 相似文献
2.
《Ceramics International》2021,47(18):25505-25513
Herein, /graphene oxide nanocomposites were fabricated by ultrasonication technique, using pure spinel ferrite and graphene oxide synthesized by sol-gel method and modified Hummers' method, respectively. The effect of graphene incorporation with ferrite nanoparticles was studied by X-ray diffraction (XRD), electrical and dielectric measurements. XRD analysis revealed the spinel phase for the ferrite sample and confirmed the formation of graphene oxide. The crystallite size was found in the range of and the porosity increased with the increase in the concentration of graphene oxide in the composites. The DC electrical resistivity of spinel ferrite was found equal to and it substantially decreased with the increase in the percentage of graphene oxide at room temperature. The real and imaginary part of relative permittivity followed the Maxwell-Wagner type of interfacial polarization. AC conductivity confirmed the conduction by hopping mechanism and increased on increasing the GO content. The coupling of magnetic ferrite with graphene oxide tunes the magneto-electrical properties for potential applications at high frequencies. 相似文献
3.
In this article, the silver-plated polyamide fabrics (SPPAFs) with high electroconductibility and shielding effectiveness were fabricated by using in situ reduction of polydopamine and chemical silvering. The effects of SPPAFs dopamine (C8H11O2N) and silver nitrate (AgNO3) concentration on surface resistivity and electromagnetic interference shielding effectiveness were studied. The results showed that the surface resistivity of SPPAFs can reach a minimum value of 0.06 ± 0.014 Ω cm−1, when C8H11O2N concentration is 4 g L−1 and the AgNO3 concentration is 120 g L−1. The shielding effectiveness of SPPAFs in the wide frequency range of 10–3000 MHz increases with the increase in the concentration of AgNO3, and increases first and stabilizes afterward with increasing C8H11O2N concentration. When the concentration of C8H11O2N and AgNO3 is 3 and 120 g L−1, respectively, mean shielding effectiveness values in the low-, medium-, and high-frequency bands are 71.3, 73.8, and 76.1 dB, respectively. Moreover, the mean shielding effectiveness values is 83.79 dB in the frequency range of 1.2–2.3 GHz. The dominant shielding mechanism of SPPAFs is the reflected electromagnetic waves and the absorption shielding effectiveness is less than 2 dB. The average electromagnetic shielding values of SPPAFs are above 67 dB after 16 weeks of storage, when C8H11O2N concentration is 4 g L−1 and the AgNO3 concentration is 80 and 100 g L−1. The prepared SPPAFs show promising applications in military textiles and smart wearable clothing. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48227. 相似文献
4.
The current study establishes the unprecedented involvement in the evolution and production of novel core–shell nanocomposites composed of nanosized titanium dioxide and aniline‐o‐phenylenediamine copolymer. TiO2@copoly(aniline and o‐phenylenediamine) (TiO2@PANI‐o‐PDA) core–shell nanocomposites were chemically synthesized in a molar ratio of 5:1 of the particular monomers and several weights of nano‐TiO2 via oxidative copolymerization. The construction of the TiO2@PANI‐o‐PDA core–shell nanocomposites was ascertained from Fourier transform IR spectroscopy, UV–visible spectroscopy and XRD. A reasonable thermal behavior for the original copolymer and the TiO2@PANI‐o‐PDA core–shell nanocomposites was investigated. The bare PANI‐o‐PDA copolymer was thermally less stable than the TiO2@PANI‐o‐PDA nanocomposites. The core–shell feature of the nanocomposites was found to have core and shell sizes of 17 nm and 19–26 nm, respectively. In addition, it was found that the addition of a high ratio of TiO2 nanoparticles increases the electrical conductivity and consequently lowers the electrical resistivity of the TiO2@PANI‐o‐PDA core–shell nanocomposites. The hybrid photocatalysts exhibit a dramatic photocatalytic efficacy of methylene blue degradation under solar light irradiation. A plausible interpretation of the photocatalytic degradation results of methylene blue is also demonstrated. Our setup introduces a facile, inexpensive, unique and efficient technique for developing new core–shell nanomaterials with various required functionalities and colloidal stabilities. © 2018 Society of Chemical Industry 相似文献
5.
《Journal of the European Ceramic Society》2020,40(12):3824-3828
Reactive hot pressing was utilized to synthesize and densify four ZrB2 ceramics with impurity contents low enough to avoid obscuring the effects of dopants on thermal properties. Nominally pure ZrB2 had a thermal conductivity of 141 ± 3 W/m K at 25 °C. Additions of 3 at% of Ti, Y, or Hf decreased the thermal conductivity by 20 %, 30 %, and 40 %, respectively. The thermal conductivity of (Zr,Hf)B2 was similar to ZrB2 synthesized from commercial powders containing the natural abundance of Hf as an impurity. This is the first study to demonstrate that Ti and Y additions decrease the thermal conductivity of ZrB2 ceramics and report intrinsic values for thermal conductivity and electrical resistivity of ZrB2 containing transition metal additions. Previous studies were unable to detect these effects because the natural abundance of Hf present masked the effects of these additions. 相似文献
6.
《Ceramics International》2020,46(13):20798-20809
The yttrium substituted cadmium ferrites having composition Cd1-xYxFe2O4 (X = 0.00, 0.125, 0.250, 0.375, 0.500) were synthesized by the co-precipitation method and sintered at 1100 °C for 6 h. Structural, morphological, electrical, optical and dielectric characteristics were explored by XRD, SEM, EDS, FTIR, I–V two probes, UV–Vis and LCR techniques.XRD results confirmed the cubic structure of spinel ferrites. A decrease in lattice constants of the prepared samples was observed with the substitution of Y ions and was attributed to the difference in ionic radii of Y3+ (0.95 Å) and Cd2+ (0.97 Å) ions. Cationic distributions, ionic radii of both tetrahedral and octahedral sites, tolerance factor, oxygen positional parameters, bond lengths, interatomic distances, positional parameters and bond length angles were calculated from XRD data. The morphology of the prepared ferrites was studied using SEM and results ratified the XRD results. EDS confirmed the presence of all inserted elements in Cd1-xYxFe2O4 composition. DC resistivity and drift mobility of soft-ferrites were found to be increased from 1.047 × 108–4.822 × 1010 Ω-cm and 5.87 × 10−12 – 1.045 × 10−14 cm2V−1s−1, respectively, at 523 K with yttrium content confirming the behavior of semiconductor materials. The optical band gap energy calculated from the UV–Vis pattern of the Cd1-xYxFe2O4 system was decreased from 3.6011 to 2.8153 eV. DC resistivity and optical band gaps exposed inverse relation. FTIR results revealed lower and upper-frequency absorption bands in the ranges of 419.31–417.01 cm−1 and 540.95–565.70 cm−1, respectively. Dielectric constant and dielectric losses were in decreasing order, while ac conductivity revealed rising behavior with increasing frequency. Results showed the potential of yttrium doped Cd nanoferrites for applications in high-frequency microwave absorbing devices. 相似文献
7.
地层压力低导致泥浆侵入深度加大,电阻率测井响应受到泥浆侵入的影响不能真正反映地层的电阻率特性。在天然气高产的储层段,深、浅电阻率测井应该有的差异被弱化,使得电阻率测井识别与评价天然气储层的应用受到制约。为此,依据电阻率测井的基本原理及泥浆侵入对双侧向测井的影响机理,研究了鄂尔多斯盆地天然气储层电阻率测井的响应特征及其在应用中存在的问题,探讨了仪器结构参数、地层视电阻率、真电阻率、泥浆侵入深度之间的关系,给出了电阻率测井泥浆侵入影响的校正方法及泥浆侵入深度的计算方法;选择了有代表性的几口井(A15井,A16井,AK2井)对方法进行了验证,改进了该地区天然气储层的识别与评价方法。 相似文献
8.
9.
测井资料在生油岩评价中的应用 总被引:2,自引:0,他引:2
介绍了生油岩的测井响应特征、有机质特点及生油岩定性、定量评价方法.依据生油岩在不同测井曲线上的响应特征,利用电阻率、声波时差、自然伽马能谱等测井信息,采用自然伽马能谱测井定性识别生油岩、声波-电阻率法定量计算生油岩参数、利用岩心分析的有机碳含量与铀、钍、钾的关系回归计算评价生油岩等不同的方法,以滋2井、林30井、莱64井生油岩的定性、定量测井评价为例,分析测井资料在生油岩评价中的应用,在对不同的计算方法的结果进行误差对比分析后,认为测井资料在生油岩评价方面的应用效果明显. 相似文献
10.