陆东凹陷油气藏烃类组成非均质性及其意义

陆东凹陷原油和油砂抽提物中烃类的宏观组成存在着明显的非均质性。在高孔隙度(>15%)储层单元中,饱和烃的含量高,占总组成的含量均大于40%,而极性化合物则相对较低,一般不足40%;相反,在低孔隙度(<15%)储层单元中,饱和烃的含量明显降低,而极性化合物则显著增加。此外,陆东凹陷原油和油砂抽提物中烃类成熟度亦存在着非均质性:在高孔隙度储层中,原油和油砂烃类的成熟度参数高,而在低孔隙度储层中原油和油砂烃类的成熟度参数低。根据原油和油砂抽提物中烃类的宏观组成特征和成熟度参数的变化规律,提出了陆东凹陷油气聚集模式。     

Application of hydrocarbon mixtures in small refrigerating and cryogenic machines

Application of hydrocarbon mixtures enables the creation of simple, reliable and durable refrigerating and cryogenic Joule–Thomson micro coolers for the temperature range of −73 to −183 °C. The temperature, thermal, power and hydraulic performances of a series of prototypes are presented. The results of tests demonstrate that small, single stage, sealed, lubricated compressors can be applied to these purposes. The start up and steady operation hydraulic performance of those machines are quite similar to the performance of domestic refrigerators. The last, together with the fact that in the studied micro coolers the lubricated compressors are used at temperatures down to −183 °C, ensures a large resource of operation. That is just the reason that holds out a hope for prospects in a broad field of applications for the studied prototypes, despite their lower power performances in contrast to gas micro coolers.     

Hydrocarbon exploration risk evaluation through uncertainty and sensitivity analyses techniques

The evaluation of the exploration risk in the oil industry is a fundamental component of the decision process related to the exploratory phase. In this paper the two basic components of the exploratory risk: trap geometry and trapped hydrocarbon quantities (fluid), are compounded in a single coherent uncertainty and sensitivity approach. The results clarify that the model geometry influences each Petroleum System Modeling step and that the geometric uncertainty is correlated with the fluid uncertainty. The geometric uncertainty evaluation makes use of geostatistical techniques that produce a number of possible realizations of the trap geometry, all compatible with available data. The evaluation of the fluid uncertainty, through a Monte Carlo methodology, allows us to compute the possible quantities of oil and gas, generated in a basin and migrated from the hydrocarbon source location to each single trap. The final result is the probability distribution of oil and gas for each trap in the basin, together with other useful indicators like: the hydrocarbon filling probability map, the closure probability map, the drainage area probability map, the spilling paths probabilities, the trap-filling scenarios.     

CFCs,HCFCs类制冷工质的替代评述与展望

从环保,经济性和使用安全性角度分析了各自的特点和局限性。指出环境不友好的过渡性替代物的应用会走技术改造的弯路,造成巨大的经济损失。并指明:只要采取适当措施就可以使用环境性能经济性能都很好的碳氢类物质作为现在的和未来的制冷剂。未来的制冷剂将不会使用氟利昂。     

Ru-catalyzed anode materials for direct hydrocarbon SOFCs

A solid oxide fuel cell using a thin ceria-based electrolyte film with a Ru-catalyzed anode was directly operated on hydrocarbons, including methane, ethane, and propane, at 600 °C. The role of the Ru catalyst in the anode reaction was to promote the reforming reaction of the unreacted hydrocarbons by the produced steam and CO₂, which avoided interference from steam and CO₂ in the gas-phase diffusion of the fuels. The resulting peak power density reached 750 mW cm⁻² with dry methane, which was comparable to the peak power density of 769 mW cm⁻² with wet (2.9 vol.% H₂O) hydrogen. More important was the fact that the cell performance was maintained at a high level regardless of the change in the methane utilization from 12 to 46% but was significantly reduced by increasing the hydrogen utilization from 13 to 42%. While the anodic reaction of hydrogen was controlled by the slow gas diffusion, the anodic reaction of methane was not subject to the onset of such a gas-diffusion process.     

应用烃类直接检测技术预测天然气藏

柴达木盆地位于青藏高原北部，是中国大型含油气盆地之一，历经４０年的勘探，发现了丰富的油气资源。柴达木盆地东部地区是第四纪沉降与沉积中心，区内第二系生储气岩厚度大、分布广、第四纪新构造运动形成的同生沉积构造发育、保存完整、具有形成大中型天然气田的地质条件。此外，由于该地区含气地层时代新、埋藏浅、成岩与胶结作用差、含气层厚度大、孔渗性好，加之构造条件简单，人文干扰小、是应用烃直接检测技术寻找天然气的有     

Speciation of the semivolatile hydrocarbon engine emissions from sunflower biodiesel

Biodiesel fuel is a very attractive alternative to conventional fuel and its effects in the engine performance and regulated emissions have been widely studied. However, the impact on unregulated individual compounds or chemical characteristics of exhaust emissions is not fully characterized. In this paper, the semivolatile fractions of the exhaust emissions of biodiesel blends and conventional fuel have been speciated. The results show great differences between the compounds emitted, especially regarding oxygenated and aromatic species. Likewise, there is a clear relationship between speciated hydrocarbons and other important emissions such as total hydrocarbons (HC), particulate matter (PM), volatile organic fraction (VOF) and mean particle diameter (Dm) of PM.     

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文章旨在通过沉积相的研究，弄清孔雀河斜坡储盖组合，解决长期以来勘探成功率极低，在油气源充足的情况条件下找不到大油气田的问题。利用单井沉积相分析、典型井岩心分析、野外剖面资料和地震测线资料研究结果，得出了塔里木盆地孔雀河地区志留系沉积特点、演化特征及平面展布规律，指出该区在志留纪的沉积是以滨海—浅海为主的海陆过渡相，在北部区域发育有三角洲；结合单井试油试气资料，研究认为该区的浅海沉积物几乎全部是砂岩，缺少泥岩盖层，因而以前所钻4口探井都以失利告终，这也是长期在该区找不到油气田的症结，而孔雀河1井正好钻在位于北部的三角洲沉积区域，该区地层具有砂、泥互层的特点，具备了较好的储集层和局部盖层，试油结果表明有24个气层，该井的东部及东北部的三角洲区域是今后勘探的有利区域。     

利用计算机进行油气资源评价和勘探决策

本文着重介绍了构成《现代勘探决策理论系统》的5个主要计算机模块,即:生油岩热演化处理、求任意曲边形面积、数学模拟预测资源量、勘探经济评价分析及决策、辅助处理等模块。该系统曾在塔里木盆地和准噶尔盆地的油气资源评价和勘探决策中发挥了作用,受到了专家和用户的好评。     

Determining actual LNAPL plume thickness: review and case study in a fractured aquifer

Determining the thickness of a LNAPL (light non-aqueous phase liquid) hydrocarbon plume in the fractured rock surrounding a borehole is a very important aspect in determining the quantity and degree of contamination of the groundwater and soil, as well as deciding on applicable remediation measures. This review aims to compare some of the field and empirical methods to eventually propose a method of confirming the plausibility of the determined thickness. General insight is supplied relating to the occurrence of groundwater in the Earth’s crust, the basic principles of multiphase flow and the properties of the three fluids of importance, being water, Jet A-1 fuel and air. From the methods applied, the field bail-down method of Hughes et al. and the mathematical approach according to CONCAWE supplied reasonable results, with the Zillox and Muntzer equation providing no rational outcome due to changing water levels from regular bailing of the LNAPL. Furthermore, practically none of these methods have been developed for deep, fractured aquifers. By plotting regular depths to water and fuel on the abscissa axis with free product thickness on the ordinate, the depth to water and depth to fuel linear plots will intersect where the free product thickness equals zero. This indicates the static water level (i.e., the ground water level prior to hydrocarbon contamination) and by subtracting this from the free product depth, a maximum product thickness is obtained.