ZnSe/CoSe/NCDPH composites as anode materials for lithium ion batteries with high capacity and long cycle

In this paper, dopamine hydrochloride (DPH) is introduced to synthesize ZIF-8@ZIF-67@DPH in the preparation of ZIF-8@ZIF-67. ZnSe/CoSe/NC_DPH (N-doped carbon) composites are calcined in a high-temperature inert atmosphere with ZIF-8@ZIF-67@DPH as the precursor, selenium powder as the selenium source. ZnSe/CoSe/NC_DPH has high discharge specific capacity, good cycle stability and outstanding rate performance. The first discharge capacity of ZnSe/CoSe/NC_DPH is 1616.6 mAh g⁻¹ at the current density of 0.1 A g⁻¹, and the reversible capacity remains at 1214.2 mAh g⁻¹ after 100 cycles, the reversible capacity is 416.7 mAh g⁻¹ after 1000 cycles at 1 A g⁻¹. Therefore, ZnSe/CoSe/NC_DPH composites provide a new step for the research and synthesis of new stable, high-capacity, and safe high-performance lithium ion batteries. The bimetallic selenide composites not only have bimetallic active sites, but also can form synergistic effect between different metal phases, which can effectively reduce the capacity attenuation caused by volume expansion and reactive stress enrichment during lithium storage of metal oxide anode materials. Meanwhile, N-doped carbon can improve the conductivity and provide more active sites to store lithium, thus improving its lithium storage capacity.     

Prediction and identification of rotary axes error of non-orthogonal five-axis machine tool

This paper proposes an efficient and automated scheme to predict and identify the position and motion errors of rotary axes on a non-orthogonal five-axis machining centre using the double ball bar (DBB) system. Based on the Denavit-Hartenberg theory, a motion deviations model for the tilting rotary axis B and rotary C of a non-orthogonal five-axis NC machine tool is established, which considers tilting rotary axis B and rotary C static deviations and dynamic deviations that total 24. After analysing the mathematical expression of the motion deviations model, the QC20 double ball bar (DBB) from the Renishaw Company is used to measure and identify the motion errors of rotary axes B and C, and a measurement scheme is designed. With the measured results, the 24 geometric deviations of rotary axes B and C can be identified intuitively and efficiently. This method provides a reference for the error identification of the non-orthogonal five-axis NC machine tool.     

高精度数控机床非均匀有理B样条曲线插补控制研究

在复杂曲面数控加工中,经常应用非均匀有理B样条曲线。介绍了非均匀有理B样条曲线插补原理,分析了传统非均匀有理B样条曲线插补方法,即泰勒展开法,确认泰勒展开法在计算精度和时效性等方面存在不足。针对泰勒展开法存在的不足,提出采用割线法进行非均匀有理B样条曲线插补。介绍了割线法插补原理,分析了迭代运算初值及终止判定问题。通过对比确认,割线法求解时间短,精度较高,可以满足高精度数控机床非均匀有理B样条曲线的插补控制要求。     

CE7120斜床身车床的数控改造

介绍了一种CE7120斜床身车床数控化改造的方案,包括机械部分改造和电气部分改造。改造后的数控车床在零件的加工精度及加工效率等方面都有明显的提高。     

数控铣削加工程序通用模块化的实现

在合理安排工艺过程的基础上,如何编制结构简洁、刀路科学的数控程序很大程度上影响着工件加工效率和质量,探讨如何合理运用子程序和刀具半径补偿功能,实现数控铣削加工程序的模块化、通用化。     

基于数控的振动机械制造

针对振动机械制造企业的生产特点 ,引入了数控技术并介绍了几种典型的数控机床及在振动机械制造中的加工特点和应用情况。采用数控机床使企业的生产效率、产品质量、经济效益均收到了令人满意的效果。     

Research on virtual dynamic optimization design for NC machine tools

Virtual dynamic optimization design can avoid the repeated process from design to trial-manufacture and test. The designer can analyze and optimize the product structures in virtual visualization environment. The design cycle is shortened and the cost is reduced. The paper analyzed the peculiarity of virtual optimization design, and put forwards the thought and flow to implement virtual optimization design. The example to optimize the internal grinder was studied via establishing precise finite element model, modifying the layout of Stiffened Plates and designing parameters of the worktable, and using the technology of modal frequency revision and the technology of multiple tuned damper. The result of optimization design compared the new grinder with the original grinder shows that the entire machine＇s first orders natural frequency is enhanced by 17%, and the response displacement of the grinding-head has dropped by 28% under the first order natural frequency and by 41% under second order natural frequency. Finally, the dynamic performance of the internal grinder was optimized.     

用编程改善数控加工的刀具痕迹

数控加工中产生的接刀痕迹,对产品的使用性能、工作寿命及可靠性有直接影响。分析了接刀痕迹产生的原因,并提出了用软件补偿的方法来改善接刀痕迹,散热器表面加工质量得到了提高,在生产中取得了较好的效果。     

数控加工的工艺设计

简述了数控加工中数控工艺的制定、数值计算以及数控程序编制的基本特点和原则,对提高工艺文件质量,更好的保证图纸要求、数控设备的完好使用等有着积极的现实意义。     

基于Pro/E的注塑模具设计与数控加工研究

介绍了利用Pro/E Wildfire软件对注塑模具设计及数控加工编程的方法。通过一个具体实例,阐述了如何利用Pro/E Wildfire软件的参数化实体建模技术实现模具设计和数控加工编程。研究结果对注塑模具设计与数控加工具有一定的参考价值。