Microstructure and properties of in-situ synthesized Cu-1 wt%TiC alloy followed by ECAP and post-annealing

A dispersion-strengthened copper alloy with 1 wt% TiC for commercial electrical-contact wires was prepared by in-situ reaction casting, grain-ultrafining by equal-channel angular pressing (ECAP) and subsequent annealing with aim to obtain excellent comprehensive performance. The results showed that fine TiC particles were in-situ synthesized in the as-cast Cu matrix and aggregated in clusters, and thus mechanical properties of the as-cast alloy deemed insufficient. Continued ECAP at 473 K significantly refined the grains of the as-cast alloy and improved the distribution of TiC particles. Due to multiple strengthening mechanisms, the ECAP-processed alloys maintained good conductivity with obviously enhanced tensile strength and hardness values. After post-ECAP annealing, the elongation and conductivity of the fine-grained copper alloy increased with the adequate tensile strength. The novel combined process endows the alloy appropriate performance to serve current high-frequency electrification railway systems.     

焙烧高岭土微球特性的研究

我国的高岭土以其成因类型齐全、储量丰富、质量优良而闻名于世。高岭土广泛应用于石油化工、造纸、功能填料、耐火材料等方面。高岭土可用作载体担载催化剂,也可用作合成沸石分子筛的原料,因此是一种潜在的理想原位晶化载体。用高岭土原位晶化技术得到的沸石分子筛具有较高的水热稳定性,解决在工业生产中的过滤问题,同时降低生产成本。本论文首先系统地研究了高岭土微球在高温焙烧过程中的性质变化,为在高岭土微球上原位生长NaY沸石分子筛的研究打下了良好的基础。     

现场FT—IR光谱电化学方法及应用研究

介绍了常规FT-IR光谱仪上的现场电化学测定,分析讨论了这一方法在溶液反应及其定量处理,修饰膜电极,金属的氧化,腐蚀与缓蚀等方面的应用。     

NO与MTPP相互作用的原位DRFTIR研究

金属卟啉配合物具有分解和还原NO的良好催化能力,如果能代替贵金属作为转化汽车排放废气NO,NO_2的催化剂,则有重要的实用价值。研究NO同金属叶啉的相互作用,是进一步探讨金属叶啉催化分解和还原NO的机理的基础。使用ESR,XPS,UV—Visible和IR等现代技术巳得到反映一部分类型NO吸附物的信息。本文中采用原位漫反射付里叶红外方法,In—Situ DRFTIR,观察到的现象更为全面。1 样品与方法     

薄互层储层井筒地应力关键影响因素分析

井筒中地应力参数主要依靠声波法测井、水力压裂施工和地面岩石力学测试,获得的地应力参数可靠性差,对地应力起决定性的关键因素还不明确。因此从岩石力学仿真数学模型出发,建立了真实地层参数的地应力仿真物理模型和力学模型;并结合薄互层储层的实际地质情况,分析了储隔层厚度、隔层泥质含量等关键因素对地应力参数的影响。研究结果表明:随着隔层厚度的增大,储隔层的应力差有变大的趋势,且下隔层与储层的应力差大于上隔层与储层的应力差;水平主应力差都随着隔层的泥质含量的升高而逐渐增大,且上隔层与储层应力差小于下隔层与储层的应力差。研究对指导岩石力学参数测井解释和储层增产改造设计具有十分重要的意义。     

电化学及现场光谱电化学方法研究在质子介质中混合价H_nAs_2Mo_(18)O_(62)~(6-)(n=2,4,6,8)多阴离子簇的电还原行为

以电化学及现场紫外可见近红外及现场红外光谱电化学方法对Dawson结构多阴离子簇As2 Mo18O6 -6 2在高氯酸酸化的乙腈溶液中的电还原过程进行了研究 ,结果表明 ,该多阴离子在质子介质中经历四步可逆的两电子还原反应 ,多阴离子簇的还原伴随着产物的质子化 ,质子化的位置在Mo—O—Mo桥键的桥氧上 ,由于质子化诱导极化作用使Mo =O双键还原后吸收峰蓝移且增强     

Microstructure evolution and reaction behavior of Cu–Ni alloy and B_4C powder system

Microstructure evolution and reaction behavior of Cu–Ni alloy and B_4C power system was studied by in-situ and static experimental investigations along with theoretical calculations. The reaction process was as follows. Firstly,B_4C decomposed into B and C atoms, and then B atoms diffused into Cu–Ni matrix, leading to the formation of Ni_2B particles. Subsequently, Ni atoms diffused into B_4C, forming a loose mixture of Ni_2B and amorphous C at the initial powder boundary. Finally, with the completion of reaction, Ni_2B particles at the powder boundary grew into a monolithic block, and then C substance was excluded out and accumulated at the edge of this monolithic Ni_2B block. It is believed that the formation of Ni_2B phase is caused by the most negative change of Gibbs free energy among all the potential reactions between Ni–B and Ni–B_4C systems.     

降雨条件下花岗岩残积土边坡失稳模式及预警阈值现场试验

降雨是诱发边坡失稳的主要因素,为探明不同降雨强度条件下花岗岩残积土边坡的失稳模式,通过75mm/h、125mm/h、150mm/h、175mm/h等4组不同降雨强度下边坡失稳现场试验,基于工程边坡原位监测试验采集的含水率-时间与位移-时间曲线研究了花岗岩残积土边坡渐进失稳破坏特征,并提出了降雨条件边坡失稳的持续时间与降雨量阈值。研究表明:降雨条件下花岗岩残积土边坡为渐进失效破坏,根据降雨强度斜坡失稳破坏可分为“浅层局部滑动”、“浅层整体滑动与崩塌”、“深层局部滑动”、“深层整体滑动”等四种模式,斜坡发生变形失稳的区域主要位于坡脚位置,坡中次之,坡顶最小。边坡深层滑动从显著变形到失稳破坏历时18~20min,而浅层滑动持续时间为25min~135min。土壤界限含水率可特征边坡失稳破坏过程,当斜坡土壤含水率上为42～45%时,斜坡开始出现开裂、蠕动变形等失稳征兆;当土壤含水率上升到47～50%时,坡面土体开始崩解并迅速发生滑坡、崩塌。     

In-situ secondary growth of nanocube-based Prussian-blue film as an ultrasensitive biosensor

A regular nanostructure has been widely confirmed to result ina marked improvement in material performance in biosensing applications.In the present study,a regular nanostructured Prussian blue(PB) film with two heterogeneous crystal layers was synthesized in-situ using a secondary growth method.A PB seed layer was first controlled to form uniform cube-like crystal nuclei through an ultrasonic reaction with a single reactant.Then,well-defined 100 nm PB nanocubes were further crystallized on this seed layer using a self-assembly approach.In order to accelerate the electron transfer rate during the enzyme reaction for glucose detection,the graphene was used as the main cross-linker to immobilize glucose oxidase on the PB film.The as-prepared biosensor exhibited high electrocatalysis and electron conductivity for the detection of trace glucose with a sensitivity of141.5 μA mM~(-1) cm~(-2),as well as excellent anti-interference ability in the presence of ascorbic acid and uric acid under a low operation potential of-0.05 V.     

不同侧压系数下复合地层变形破坏特征数值模拟

针对中国中西部挤压造山带大埋深不同侧压系数(0.5~2.0)下复合地层在工程开挖扰动下复杂叠加的变形破坏特征,采用有限差分程序FLAC3D对3种不同组合型式的复合地层开展了数值模拟研究。同时结合软岩和硬岩解析解的分析对比,发现开挖卸荷作用下复合地层位移量比均质软岩小,前者随侧压系数增加位移量较大的点由顶拱向边墙转移变化。硬岩中富集的主应力比软岩中高。软岩塑性区半径最大的是前软后硬型,比上下叠置型复合地层的结果大很多。后者接近该深度下的均质软岩隧道的塑性圈半径。本文结果可为复合地层中隧道工程设计和施工提供参考。